1, 2-二(四唑-5-基)乙烷Mg盐和Ca盐的合成, 结构与热分析

Xin Rui Li; Xiao Ming Yang; Hai Bo Li; Zhi Min Li; Lin Wang; Tong Lai Zhang

doi:10.11943/CJEM2020014

1, 2-二(四唑-5-基)乙烷Mg盐和Ca盐的合成, 结构与热分析

Translated title of the contribution: Magnesium and Calcium Salts of 1, 2-Bis(tetrazol-5-yl)ethane: Synthesis, Crystal Structures and Thermal Analysis

Xin Rui Li, Xiao Ming Yang, Hai Bo Li, Zhi Min Li, Lin Wang, Tong Lai Zhang^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

To develop new series of tetrazole energetic materials, two new compounds, magnesium and calcium salts of 1, 2-bis(tetrazol-5-yl)ethane ([Mg(BTE)(H₂O)₄]_n•nH₂O and [Ca(BTE)(H₂O)₅]_n) were prepared. Their single crystals were obtained by solvent evaporation method. The structures were fully characterized by X-ray single crystal diffraction, elemental analysis and FT-IR method. The thermal decomposition behavior of two compounds were studied by DSC and TG-DTG methods Their non-isothermal kinetic parameters were calculated by the Kissinger method and Ozawa method. Results show that [Mg(BTE)(H₂O)₄]_n•nH₂O belongs to monoclinic system, space group P2₁/c, cell parameters: a=9.0367(18) Å, b=9.1427(18) Å, c=7.4491(15) Å, β=103.51(3)°, Z=2. [Ca(BTE)(H₂O)₅]_n belongs to orthorhombic system, space group Pnnm, cell parameters: a=11.205(2) Å, b=13.605(3) Å, c=7.1415(14) Å, Z=4. The temperatures of first exothermic peak for [Mg(BTE)(H₂O)₄]_n•nH₂O and [Ca(BTE)(H₂O)₅]_n are 387.7℃ and 415.8℃, respectively.

Translated title of the contribution	Magnesium and Calcium Salts of 1, 2-Bis(tetrazol-5-yl)ethane: Synthesis, Crystal Structures and Thermal Analysis
Original language	Chinese (Traditional)
Pages (from-to)	1036-1042
Number of pages	7
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	28
Issue number	11
DOIs	https://doi.org/10.11943/CJEM2020014
Publication status	Published - 25 Nov 2020

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@article{bf9bb49327644b56aebfcae586eebb87,

title = "1, 2-二(四唑-5-基)乙烷Mg盐和Ca盐的合成, 结构与热分析",

abstract = "To develop new series of tetrazole energetic materials, two new compounds, magnesium and calcium salts of 1, 2-bis(tetrazol-5-yl)ethane ([Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n) were prepared. Their single crystals were obtained by solvent evaporation method. The structures were fully characterized by X-ray single crystal diffraction, elemental analysis and FT-IR method. The thermal decomposition behavior of two compounds were studied by DSC and TG-DTG methods Their non-isothermal kinetic parameters were calculated by the Kissinger method and Ozawa method. Results show that [Mg(BTE)(H2O)4]n•nH2O belongs to monoclinic system, space group P21/c, cell parameters: a=9.0367(18) {\AA}, b=9.1427(18) {\AA}, c=7.4491(15) {\AA}, β=103.51(3)°, Z=2. [Ca(BTE)(H2O)5]n belongs to orthorhombic system, space group Pnnm, cell parameters: a=11.205(2) {\AA}, b=13.605(3) {\AA}, c=7.1415(14) {\AA}, Z=4. The temperatures of first exothermic peak for [Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n are 387.7℃ and 415.8℃, respectively.",

keywords = "1, 2-bis(tetrazol-5-yl)ethane, Crystal structure, Synthesis, Tetrazole, Thermal analysis",

author = "Li, {Xin Rui} and Yang, {Xiao Ming} and Li, {Hai Bo} and Li, {Zhi Min} and Lin Wang and Zhang, {Tong Lai}",

year = "2020",

month = nov,

day = "25",

doi = "10.11943/CJEM2020014",

language = "繁体中文",

volume = "28",

pages = "1036--1042",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "11",

}

TY - JOUR

T1 - 1, 2-二(四唑-5-基)乙烷Mg盐和Ca盐的合成, 结构与热分析

AU - Li, Xin Rui

AU - Yang, Xiao Ming

AU - Li, Hai Bo

AU - Li, Zhi Min

AU - Wang, Lin

AU - Zhang, Tong Lai

PY - 2020/11/25

Y1 - 2020/11/25

N2 - To develop new series of tetrazole energetic materials, two new compounds, magnesium and calcium salts of 1, 2-bis(tetrazol-5-yl)ethane ([Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n) were prepared. Their single crystals were obtained by solvent evaporation method. The structures were fully characterized by X-ray single crystal diffraction, elemental analysis and FT-IR method. The thermal decomposition behavior of two compounds were studied by DSC and TG-DTG methods Their non-isothermal kinetic parameters were calculated by the Kissinger method and Ozawa method. Results show that [Mg(BTE)(H2O)4]n•nH2O belongs to monoclinic system, space group P21/c, cell parameters: a=9.0367(18) Å, b=9.1427(18) Å, c=7.4491(15) Å, β=103.51(3)°, Z=2. [Ca(BTE)(H2O)5]n belongs to orthorhombic system, space group Pnnm, cell parameters: a=11.205(2) Å, b=13.605(3) Å, c=7.1415(14) Å, Z=4. The temperatures of first exothermic peak for [Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n are 387.7℃ and 415.8℃, respectively.

AB - To develop new series of tetrazole energetic materials, two new compounds, magnesium and calcium salts of 1, 2-bis(tetrazol-5-yl)ethane ([Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n) were prepared. Their single crystals were obtained by solvent evaporation method. The structures were fully characterized by X-ray single crystal diffraction, elemental analysis and FT-IR method. The thermal decomposition behavior of two compounds were studied by DSC and TG-DTG methods Their non-isothermal kinetic parameters were calculated by the Kissinger method and Ozawa method. Results show that [Mg(BTE)(H2O)4]n•nH2O belongs to monoclinic system, space group P21/c, cell parameters: a=9.0367(18) Å, b=9.1427(18) Å, c=7.4491(15) Å, β=103.51(3)°, Z=2. [Ca(BTE)(H2O)5]n belongs to orthorhombic system, space group Pnnm, cell parameters: a=11.205(2) Å, b=13.605(3) Å, c=7.1415(14) Å, Z=4. The temperatures of first exothermic peak for [Mg(BTE)(H2O)4]n•nH2O and [Ca(BTE)(H2O)5]n are 387.7℃ and 415.8℃, respectively.

KW - 1, 2-bis(tetrazol-5-yl)ethane

KW - Crystal structure

KW - Synthesis

KW - Tetrazole

KW - Thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=85096495118&partnerID=8YFLogxK

U2 - 10.11943/CJEM2020014

DO - 10.11943/CJEM2020014

M3 - 文章

AN - SCOPUS:85096495118

SN - 1006-9941

VL - 28

SP - 1036

EP - 1042

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 11

ER -

1, 2-二(四唑-5-基)乙烷Mg盐和Ca盐的合成, 结构与热分析

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