π-Conjugation-directed highly selective adsorption of benzene over cyclohexane

Cai Xia Ren; Li Xuan Cai; Cheng Chen; Bin Tan; Ya Jun Zhang; Jie Zhang

doi:10.1039/c4ta01231c

π-Conjugation-directed highly selective adsorption of benzene over cyclohexane

Cai Xia Ren, Li Xuan Cai, Cheng Chen, Bin Tan, Ya Jun Zhang, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

Crystalline materials with large tailor-made channels have been made by an isoreticular synthesis strategy, which includes a successful adjustment of the π-conjugation over a framework skeleton allowing target recognition for aromatic molecules. The selective absorption of benzene over cyclohexane has been achieved, with a significant increase in benzene uptake with the improvement of the degree of π-conjugation.

Original language	English
Pages (from-to)	9015-9019
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	2
Issue number	24
DOIs	https://doi.org/10.1039/c4ta01231c
Publication status	Published - 28 Jun 2014
Externally published	Yes

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title = "π-Conjugation-directed highly selective adsorption of benzene over cyclohexane",

abstract = "Crystalline materials with large tailor-made channels have been made by an isoreticular synthesis strategy, which includes a successful adjustment of the π-conjugation over a framework skeleton allowing target recognition for aromatic molecules. The selective absorption of benzene over cyclohexane has been achieved, with a significant increase in benzene uptake with the improvement of the degree of π-conjugation.",

author = "Ren, {Cai Xia} and Cai, {Li Xuan} and Cheng Chen and Bin Tan and Zhang, {Ya Jun} and Jie Zhang",

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AU - Ren, Cai Xia

AU - Cai, Li Xuan

AU - Chen, Cheng

AU - Tan, Bin

AU - Zhang, Ya Jun

AU - Zhang, Jie

PY - 2014/6/28

Y1 - 2014/6/28

N2 - Crystalline materials with large tailor-made channels have been made by an isoreticular synthesis strategy, which includes a successful adjustment of the π-conjugation over a framework skeleton allowing target recognition for aromatic molecules. The selective absorption of benzene over cyclohexane has been achieved, with a significant increase in benzene uptake with the improvement of the degree of π-conjugation.

AB - Crystalline materials with large tailor-made channels have been made by an isoreticular synthesis strategy, which includes a successful adjustment of the π-conjugation over a framework skeleton allowing target recognition for aromatic molecules. The selective absorption of benzene over cyclohexane has been achieved, with a significant increase in benzene uptake with the improvement of the degree of π-conjugation.

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U2 - 10.1039/c4ta01231c

DO - 10.1039/c4ta01231c

M3 - Article

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EP - 9019

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 24

ER -

π-Conjugation-directed highly selective adsorption of benzene over cyclohexane

Abstract

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