Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer

Lan Fen Chen; Jie Zhang; Li Jun Song; Zhan Feng Ju

doi:10.1016/j.inoche.2005.03.019

Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ₂-aqua)bis(μ₂- carboxylate)-bridged manganese polymer

Lan Fen Chen, Jie Zhang^*, Li Jun Song, Zhan Feng Ju

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

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39 引用（Scopus）

摘要

A manganese coordination polymer [Mn₂(NTC)(H₂O) ₂]_n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H ₄NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

源语言	英语
页（从-至）	555-558
页数	4
期刊	Inorganic Chemistry Communications
卷	8
期	6
DOI	https://doi.org/10.1016/j.inoche.2005.03.019
出版状态	已出版 - 6月 2005
已对外发布	是

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@article{00f615fc9ab04261937b86cdbe478d7d,

title = "Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer",

abstract = "A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.",

keywords = "1,4,5,8-Naphthalenetetracarboxylate, Coordination polymer, Crystal structure, Magnetic, Manganese(II) complex",

author = "Chen, {Lan Fen} and Jie Zhang and Song, {Li Jun} and Ju, {Zhan Feng}",

year = "2005",

month = jun,

doi = "10.1016/j.inoche.2005.03.019",

language = "English",

volume = "8",

pages = "555--558",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

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TY - JOUR

T1 - Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer

AU - Chen, Lan Fen

AU - Zhang, Jie

AU - Song, Li Jun

AU - Ju, Zhan Feng

PY - 2005/6

Y1 - 2005/6

N2 - A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

AB - A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

KW - 1,4,5,8-Naphthalenetetracarboxylate

KW - Coordination polymer

KW - Crystal structure

KW - Magnetic

KW - Manganese(II) complex

UR - http://www.scopus.com/inward/record.url?scp=18844432280&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2005.03.019

DO - 10.1016/j.inoche.2005.03.019

M3 - Article

AN - SCOPUS:18844432280

SN - 1387-7003

VL - 8

SP - 555

EP - 558

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer

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Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ₂-aqua)bis(μ₂- carboxylate)-bridged manganese polymer