New route for the catalytic synthesis of dimethyl carbonate

Zhi Ming Gao; Jun Hua Su; Xiu Zhi Chen; Chang Wen Hu

New route for the catalytic synthesis of dimethyl carbonate

Zhi Ming Gao^*, Jun Hua Su, Xiu Zhi Chen, Chang Wen Hu

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Synthesis of dimethyl carbonate (DMC) from propylene oxide (PO), carbon dioxide and methanol was investigated. Tetrabutyl ammonium bromide and sodium methoxide were used as catalyst for the reaction. It was found that under the reaction conditions of T = 423 K, P = 4 MPa selectivity of DMC was 55.8%, and selectivity of the by products was 1.4%, when the two components of the catalyst were added separately in two steps. These results were much better than those of the case when the two components were added simultaneously.

源语言	英语
页（从-至）	651-654
页数	4
期刊	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
卷	26
期	7
出版状态	已出版 - 7月 2006

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{8cb51e8ad2e94e0a8b774f40ad60770a,

title = "New route for the catalytic synthesis of dimethyl carbonate",

abstract = "Synthesis of dimethyl carbonate (DMC) from propylene oxide (PO), carbon dioxide and methanol was investigated. Tetrabutyl ammonium bromide and sodium methoxide were used as catalyst for the reaction. It was found that under the reaction conditions of T = 423 K, P = 4 MPa selectivity of DMC was 55.8%, and selectivity of the by products was 1.4%, when the two components of the catalyst were added separately in two steps. These results were much better than those of the case when the two components were added simultaneously.",

keywords = "Carbon dioxide, Catalyst, Dimethyl carbonate, Propylene oxide",

author = "Gao, {Zhi Ming} and Su, {Jun Hua} and Chen, {Xiu Zhi} and Hu, {Chang Wen}",

year = "2006",

month = jul,

language = "English",

volume = "26",

pages = "651--654",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "7",

}

TY - JOUR

T1 - New route for the catalytic synthesis of dimethyl carbonate

AU - Gao, Zhi Ming

AU - Su, Jun Hua

AU - Chen, Xiu Zhi

AU - Hu, Chang Wen

PY - 2006/7

Y1 - 2006/7

N2 - Synthesis of dimethyl carbonate (DMC) from propylene oxide (PO), carbon dioxide and methanol was investigated. Tetrabutyl ammonium bromide and sodium methoxide were used as catalyst for the reaction. It was found that under the reaction conditions of T = 423 K, P = 4 MPa selectivity of DMC was 55.8%, and selectivity of the by products was 1.4%, when the two components of the catalyst were added separately in two steps. These results were much better than those of the case when the two components were added simultaneously.

AB - Synthesis of dimethyl carbonate (DMC) from propylene oxide (PO), carbon dioxide and methanol was investigated. Tetrabutyl ammonium bromide and sodium methoxide were used as catalyst for the reaction. It was found that under the reaction conditions of T = 423 K, P = 4 MPa selectivity of DMC was 55.8%, and selectivity of the by products was 1.4%, when the two components of the catalyst were added separately in two steps. These results were much better than those of the case when the two components were added simultaneously.

KW - Carbon dioxide

KW - Catalyst

KW - Dimethyl carbonate

KW - Propylene oxide

UR - http://www.scopus.com/inward/record.url?scp=33748684443&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33748684443

SN - 1001-0645

VL - 26

SP - 651

EP - 654

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 7

ER -

New route for the catalytic synthesis of dimethyl carbonate

摘要

其它文件与链接

指纹

引用此