N-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl} azanide trichloridostannate(II)

Xiaoli Ma*, Shuai Sun, Pengfei Hao, Ying Yang, Zhi Yang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

In the title compound, (C28H43N2) [SnCl3], two pairs of molecular species are present in the asymmetric unit. The employed α-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N - C= 1.264 (4) and 1.516 (4) Å]. One of the C=N double bonds was oxidized to C - N, which is consistent with the bond length of 1.516 (4) Å. Meanwhile SnIV was reduced to SnII. The (SnCl)3 - anion is trigonal-pyramidal. In the crystal, molecules are linked by C - H⋯Cl, N - H⋯Cl, N - H⋯N and C - H⋯N bonds. The crystal studied was twinned by pseudo-merohedry.

源语言英语
页(从-至)m719-m720
期刊Acta Crystallographica Section E: Structure Reports Online
68
6
DOI
出版状态已出版 - 6月 2012

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Ma, X., Sun, S., Hao, P., Yang, Y., & Yang, Z. (2012). N-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl} azanide trichloridostannate(II). Acta Crystallographica Section E: Structure Reports Online, 68(6), m719-m720. https://doi.org/10.1107/S1600536812014729