Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates

Jun Wei Zhao; Shou Tian Zheng; Zhao Hui Li; Guo Yu Yang

doi:10.1039/b809338e

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 6⁵·8 CdSO₄-type 3-D framework built by hexa-Cu^II sandwiched polyoxotungstates

Jun Wei Zhao, Shou Tian Zheng, Zhao Hui Li, Guo Yu Yang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

60 引用（Scopus）

摘要

A 6⁵·8 CdSO₄-type 3-D framework built by hexa-Cu^II sandwiched polyoxotungstates [Cu(en)₂]₂[Cu(deta)(H₂O)]₂[Cu₆(en)₂(H₂O)₂(B-α-GeW₉O₃₄)₂]·6H₂O (1) (en = ethylenediamine and deta = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrometry, thermogravimetric analysis and single-crystal X-ray diffraction. To the best of our knowledge, 1 represents the first 3-D TMSP with 6⁵·8 CdSO₄ topology in polyoxometalate chemistry. Magnetic measurements performed on 1 indicate the occurrence of ferromagnetic interactions within the copper ions and the coupling constants can be determined.

源语言	英语
页（从-至）	1300-1306
页数	7
期刊	Journal of the Chemical Society. Dalton Transactions
期	8
DOI	https://doi.org/10.1039/b809338e
出版状态	已出版 - 16 1月 2009
已对外发布	是

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@article{81d4b1189a73441da1ece184c9bad22d,

title = "Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates",

abstract = "A 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates [Cu(en)2]2[Cu(deta)(H2O)]2[Cu6(en)2(H2O)2(B-α-GeW9O34)2]·6H2O (1) (en = ethylenediamine and deta = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrometry, thermogravimetric analysis and single-crystal X-ray diffraction. To the best of our knowledge, 1 represents the first 3-D TMSP with 65·8 CdSO4 topology in polyoxometalate chemistry. Magnetic measurements performed on 1 indicate the occurrence of ferromagnetic interactions within the copper ions and the coupling constants can be determined.",

author = "Zhao, {Jun Wei} and Zheng, {Shou Tian} and Li, {Zhao Hui} and Yang, {Guo Yu}",

year = "2009",

month = jan,

day = "16",

doi = "10.1039/b809338e",

language = "English",

pages = "1300--1306",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "8",

}

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 6⁵·8 CdSO₄-type 3-D framework built by hexa-Cu^II sandwiched polyoxotungstates. / Zhao, Jun Wei; Zheng, Shou Tian; Li, Zhao Hui 等.
在: Journal of the Chemical Society. Dalton Transactions, 号码 8, 16.01.2009, 页码 1300-1306.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions

T2 - First 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates

AU - Zhao, Jun Wei

AU - Zheng, Shou Tian

AU - Li, Zhao Hui

AU - Yang, Guo Yu

PY - 2009/1/16

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AB - A 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates [Cu(en)2]2[Cu(deta)(H2O)]2[Cu6(en)2(H2O)2(B-α-GeW9O34)2]·6H2O (1) (en = ethylenediamine and deta = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrometry, thermogravimetric analysis and single-crystal X-ray diffraction. To the best of our knowledge, 1 represents the first 3-D TMSP with 65·8 CdSO4 topology in polyoxometalate chemistry. Magnetic measurements performed on 1 indicate the occurrence of ferromagnetic interactions within the copper ions and the coupling constants can be determined.

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Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates

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Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: First 6⁵·8 CdSO₄-type 3-D framework built by hexa-Cu^II sandwiched polyoxotungstates