Two novel metal borates with three-dimensional open-framework layers constructed from [M2B8O20(OH)2] (M = Al, Ga) cluster units

Qi Wei; Lu Li; Lin Cheng; Qin Meng; Guo Yu Yang

doi:10.1039/c4dt00652f

Two novel metal borates with three-dimensional open-framework layers constructed from [M₂B₈O₂₀(OH)₂] (M = Al, Ga) cluster units

Qi Wei, Lu Li, Lin Cheng, Qin Meng, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Two novel metal borates, Ba[MB₄O₈(OH)]·H ₂O (M = Al/Ga), with a three-dimensional open-framework layer have been synthesized under hydro(solvo)thermal conditions, in which the Al ³⁺/Ga³⁺ ions have been successfully introduced into the oxoboron cluster backbone and further linked together to form the open-framework layer composed of the [M₂B₈O₂₀(OH) ₂] cluster units. The half-unit [MB₄O₁₁(OH)] can be viewed as analogous to the known [B₅O₉(OH)] cluster. Interestingly, the rare M-O-M linkages play a crucial role in forming the open-framework layer.

Original language	English
Pages (from-to)	9427-9430
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	25
DOIs	https://doi.org/10.1039/c4dt00652f
Publication status	Published - 7 Jul 2014

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title = "Two novel metal borates with three-dimensional open-framework layers constructed from [M2B8O20(OH)2] (M = Al, Ga) cluster units",

abstract = "Two novel metal borates, Ba[MB4O8(OH)]·H 2O (M = Al/Ga), with a three-dimensional open-framework layer have been synthesized under hydro(solvo)thermal conditions, in which the Al 3+/Ga3+ ions have been successfully introduced into the oxoboron cluster backbone and further linked together to form the open-framework layer composed of the [M2B8O20(OH) 2] cluster units. The half-unit [MB4O11(OH)] can be viewed as analogous to the known [B5O9(OH)] cluster. Interestingly, the rare M-O-M linkages play a crucial role in forming the open-framework layer.",

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AU - Wei, Qi

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AU - Cheng, Lin

AU - Meng, Qin

AU - Yang, Guo Yu

PY - 2014/7/7

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N2 - Two novel metal borates, Ba[MB4O8(OH)]·H 2O (M = Al/Ga), with a three-dimensional open-framework layer have been synthesized under hydro(solvo)thermal conditions, in which the Al 3+/Ga3+ ions have been successfully introduced into the oxoboron cluster backbone and further linked together to form the open-framework layer composed of the [M2B8O20(OH) 2] cluster units. The half-unit [MB4O11(OH)] can be viewed as analogous to the known [B5O9(OH)] cluster. Interestingly, the rare M-O-M linkages play a crucial role in forming the open-framework layer.

AB - Two novel metal borates, Ba[MB4O8(OH)]·H 2O (M = Al/Ga), with a three-dimensional open-framework layer have been synthesized under hydro(solvo)thermal conditions, in which the Al 3+/Ga3+ ions have been successfully introduced into the oxoboron cluster backbone and further linked together to form the open-framework layer composed of the [M2B8O20(OH) 2] cluster units. The half-unit [MB4O11(OH)] can be viewed as analogous to the known [B5O9(OH)] cluster. Interestingly, the rare M-O-M linkages play a crucial role in forming the open-framework layer.

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Two novel metal borates with three-dimensional open-framework layers constructed from [M₂B₈O₂₀(OH)₂] (M = Al, Ga) cluster units

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