TY - JOUR
T1 - Two 2-fold interpenetrated frameworks showing different topologies based on the isomerous benzenedicarboxylate mixed with a flexible N,N′-type ligand
AU - Chen, Pang Kuan
AU - Che, Yun Xia
AU - Xue, Lin
AU - Zheng, Ji Min
PY - 2006/11
Y1 - 2006/11
N2 - This paper presents two 2-fold parallel interpenetrated polymers, namely ZnCo(bpp)(m-BDC)2 (1) and Co(bpp)(p-BDC)(2), based on isomerous 1,3-benzenedicarboxylate (m-BDC) and 1,4-benzenedicarboxylate (p-BDC). Compounds 1 and 2 have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR, ICP, TGA, DSC, and element analysis. 1 crystallizes in the triclinic space group P1 and affords a three-dimensional (3D) six-connected α-Po network, whereas 2 crystallizes in the orthorhombic space group Pbca and gives an usual 2D four-connected 44 grid. These interpenetrated topologies should be attributed to the high functionality and adaptability of the 1,3-bis(4-pyridyl)propane (bpp) ligand.
AB - This paper presents two 2-fold parallel interpenetrated polymers, namely ZnCo(bpp)(m-BDC)2 (1) and Co(bpp)(p-BDC)(2), based on isomerous 1,3-benzenedicarboxylate (m-BDC) and 1,4-benzenedicarboxylate (p-BDC). Compounds 1 and 2 have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR, ICP, TGA, DSC, and element analysis. 1 crystallizes in the triclinic space group P1 and affords a three-dimensional (3D) six-connected α-Po network, whereas 2 crystallizes in the orthorhombic space group Pbca and gives an usual 2D four-connected 44 grid. These interpenetrated topologies should be attributed to the high functionality and adaptability of the 1,3-bis(4-pyridyl)propane (bpp) ligand.
UR - http://www.scopus.com/inward/record.url?scp=33751274826&partnerID=8YFLogxK
U2 - 10.1021/cg0602717
DO - 10.1021/cg0602717
M3 - Article
AN - SCOPUS:33751274826
SN - 1528-7483
VL - 6
SP - 2517
EP - 2522
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 11
ER -