Tuning the wavelength of electrochemiluminescence by anodic potential: A design using non-Kekulé-structured iridium-ruthenium luminophores

Michael Schmittel*, Qinghai Shu, Mehmet Emin Cinar

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

43 Citations (Scopus)

Abstract

Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(iii)-Ru(ii)-Ir(iii) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.

Original languageEnglish
Pages (from-to)6064-6068
Number of pages5
JournalDalton Transactions
Volume41
Issue number20
DOIs
Publication statusPublished - 28 May 2012
Externally publishedYes

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