Three new imidazole-functionalized hexanuclear oxidovanadium clusters with exceptional catalytic oxidation properties for alcohols

Baokuan Chen; Xianqiang Huang; Boe Wang; Zhengguo Lin; Jufang Hu; Yingnan Chi; Changwen Hu

doi:10.1002/chem.201203854

Three new imidazole-functionalized hexanuclear oxidovanadium clusters with exceptional catalytic oxidation properties for alcohols

Baokuan Chen, Xianqiang Huang, Boe Wang^*, Zhengguo Lin, Jufang Hu, Yingnan Chi, Changwen Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Cluster cat: Three new imidazole-functionalized neutral hexanuclear vanadium clusters have been prepared, one of which shows exceptional catalytic activity in the selective aerobic oxidation of alcohols (see scheme). Furthermore, these new polyoxovanadium clusters can be readily recycled and reused with unchanged catalytic activity. A plausible catalytic cycle is also proposed.

Original language	English
Pages (from-to)	4408-4413
Number of pages	6
Journal	Chemistry - A European Journal
Volume	19
Issue number	14
DOIs	https://doi.org/10.1002/chem.201203854
Publication status	Published - 2 Apr 2013
Externally published	Yes

Keywords

alcohols
imidazoles
ligands
oxidation
polyoxometalates
vanadium

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10.1002/chem.201203854

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abstract = "Cluster cat: Three new imidazole-functionalized neutral hexanuclear vanadium clusters have been prepared, one of which shows exceptional catalytic activity in the selective aerobic oxidation of alcohols (see scheme). Furthermore, these new polyoxovanadium clusters can be readily recycled and reused with unchanged catalytic activity. A plausible catalytic cycle is also proposed.",

keywords = "alcohols, imidazoles, ligands, oxidation, polyoxometalates, vanadium",

author = "Baokuan Chen and Xianqiang Huang and Boe Wang and Zhengguo Lin and Jufang Hu and Yingnan Chi and Changwen Hu",

year = "2013",

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T1 - Three new imidazole-functionalized hexanuclear oxidovanadium clusters with exceptional catalytic oxidation properties for alcohols

AU - Chen, Baokuan

AU - Huang, Xianqiang

AU - Wang, Boe

AU - Lin, Zhengguo

AU - Hu, Jufang

AU - Chi, Yingnan

AU - Hu, Changwen

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Cluster cat: Three new imidazole-functionalized neutral hexanuclear vanadium clusters have been prepared, one of which shows exceptional catalytic activity in the selective aerobic oxidation of alcohols (see scheme). Furthermore, these new polyoxovanadium clusters can be readily recycled and reused with unchanged catalytic activity. A plausible catalytic cycle is also proposed.

AB - Cluster cat: Three new imidazole-functionalized neutral hexanuclear vanadium clusters have been prepared, one of which shows exceptional catalytic activity in the selective aerobic oxidation of alcohols (see scheme). Furthermore, these new polyoxovanadium clusters can be readily recycled and reused with unchanged catalytic activity. A plausible catalytic cycle is also proposed.

KW - alcohols

KW - imidazoles

KW - ligands

KW - oxidation

KW - polyoxometalates

KW - vanadium

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U2 - 10.1002/chem.201203854

DO - 10.1002/chem.201203854

M3 - Article

AN - SCOPUS:84875358743

SN - 0947-6539

VL - 19

SP - 4408

EP - 4413

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 14

ER -

Three new imidazole-functionalized hexanuclear oxidovanadium clusters with exceptional catalytic oxidation properties for alcohols

Abstract

Keywords

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