Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic

Minghui Xu; Valeri Smolenski; Qi Liu; Alena Novoselova; Kewei Jiang; Jing Yu; Jingyuan Liu; Rongrong Chen; Hongsen Zhang; Milin Zhang; Jun Wang

doi:10.1016/j.jct.2020.106260

Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic

Minghui Xu, Valeri Smolenski^*, Qi Liu, Alena Novoselova, Kewei Jiang, Jing Yu, Jingyuan Liu, Rongrong Chen, Hongsen Zhang, Milin Zhang, Jun Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The interaction of oxygen and cerium-free ions in molten 3LiCl-2KCl eutectic in the temperature range of (723–823) K was studied by the method of potentiometric titration using YZME electrodes. Stable states of cerium compounds in the Ce–O system and the mechanism of interaction of Ce³⁺ with O²⁻ ions have been established. The solubility constants of cerium oxychloride and oxide compounds at different temperatures were determined. Principal thermodynamic data of CeOCl and Ce₂O₃ were calculated. The Pourbaix (potential-pO²⁻) diagram was drawn and summarizes the properties of stable cerium species in the melt.

Original language	English
Article number	106260
Journal	Journal of Chemical Thermodynamics
Volume	152
DOIs	https://doi.org/10.1016/j.jct.2020.106260
Publication status	Published - Jan 2021
Externally published	Yes

Keywords

Cerium trichloride
Molten salt
Potentiometric titration
Pourbaix diagram
Thermodynamics

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10.1016/j.jct.2020.106260

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Xu, M., Smolenski, V., Liu, Q., Novoselova, A., Jiang, K., Yu, J., Liu, J., Chen, R., Zhang, H., Zhang, M., & Wang, J. (2021). Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic. Journal of Chemical Thermodynamics, 152, Article 106260. https://doi.org/10.1016/j.jct.2020.106260

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title = "Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic",

abstract = "The interaction of oxygen and cerium-free ions in molten 3LiCl-2KCl eutectic in the temperature range of (723–823) K was studied by the method of potentiometric titration using YZME electrodes. Stable states of cerium compounds in the Ce–O system and the mechanism of interaction of Ce3+ with O2− ions have been established. The solubility constants of cerium oxychloride and oxide compounds at different temperatures were determined. Principal thermodynamic data of CeOCl and Ce2O3 were calculated. The Pourbaix (potential-pO2−) diagram was drawn and summarizes the properties of stable cerium species in the melt.",

keywords = "Cerium trichloride, Molten salt, Potentiometric titration, Pourbaix diagram, Thermodynamics",

author = "Minghui Xu and Valeri Smolenski and Qi Liu and Alena Novoselova and Kewei Jiang and Jing Yu and Jingyuan Liu and Rongrong Chen and Hongsen Zhang and Milin Zhang and Jun Wang",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd",

year = "2021",

month = jan,

doi = "10.1016/j.jct.2020.106260",

language = "English",

volume = "152",

journal = "Journal of Chemical Thermodynamics",

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TY - JOUR

T1 - Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic

AU - Xu, Minghui

AU - Smolenski, Valeri

AU - Liu, Qi

AU - Novoselova, Alena

AU - Jiang, Kewei

AU - Yu, Jing

AU - Liu, Jingyuan

AU - Chen, Rongrong

AU - Zhang, Hongsen

AU - Zhang, Milin

AU - Wang, Jun

PY - 2021/1

Y1 - 2021/1

N2 - The interaction of oxygen and cerium-free ions in molten 3LiCl-2KCl eutectic in the temperature range of (723–823) K was studied by the method of potentiometric titration using YZME electrodes. Stable states of cerium compounds in the Ce–O system and the mechanism of interaction of Ce3+ with O2− ions have been established. The solubility constants of cerium oxychloride and oxide compounds at different temperatures were determined. Principal thermodynamic data of CeOCl and Ce2O3 were calculated. The Pourbaix (potential-pO2−) diagram was drawn and summarizes the properties of stable cerium species in the melt.

AB - The interaction of oxygen and cerium-free ions in molten 3LiCl-2KCl eutectic in the temperature range of (723–823) K was studied by the method of potentiometric titration using YZME electrodes. Stable states of cerium compounds in the Ce–O system and the mechanism of interaction of Ce3+ with O2− ions have been established. The solubility constants of cerium oxychloride and oxide compounds at different temperatures were determined. Principal thermodynamic data of CeOCl and Ce2O3 were calculated. The Pourbaix (potential-pO2−) diagram was drawn and summarizes the properties of stable cerium species in the melt.

KW - Cerium trichloride

KW - Molten salt

KW - Potentiometric titration

KW - Pourbaix diagram

KW - Thermodynamics

UR - http://www.scopus.com/inward/record.url?scp=85090420147&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2020.106260

DO - 10.1016/j.jct.2020.106260

M3 - Article

AN - SCOPUS:85090420147

SN - 0021-9614

VL - 152

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

M1 - 106260

ER -

Thermodynamic properties of stable states cerium compounds in fused 3LiCl-2KCl eutectic

Abstract

Keywords

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