Abstract
A new coordination compound was prepared by mixing aqueous solution of carbohydrazide and manganese perchlorate. It was also characterized by elemental analysis, IR and DSC analysis. The molecular and crystal structure of perchlorate tricarbohydrazide Manganese (II) was determined by X-ray crystallography. (The crystalline is monoclinic with space group P2 1/n. The coordination compound could be expressed in the formula of [Mn(CHZ)3](C1O4)2 with crystal parameters: a = 1.0197(2)nm, b = 0.8593(1)nm, c = 2.1412(3)nm, β = 100.86, V = 1.8426(5)nm3, Z = 4. The results suggest that all carbohydrazide molecules coordinated with central ion as bidentates through oxygen atom of carbonyl group and one terminal nitrogen atom, and linked with Manganese to form three five-number rings.
| Original language | English |
|---|---|
| Pages (from-to) | 13-19 |
| Number of pages | 7 |
| Journal | Chemical Journal on Internet |
| Volume | 2 |
| Issue number | 5 |
| Publication status | Published - 14 May 2000 |
Keywords
- Carbohydrazide
- Crystal structure
- Manganese perchlorate
- Molecular structure
- Preparation