The first organo-templated cobalt phosphate with a zeolite topology

Hong Ming Yuan; Jie Sheng Chen; Guang Shan Zhu; Ji Yang Li; Ji Hong Yu; Guang Di Yang; Ru Ren Xu

doi:10.1021/ic990719b

The first organo-templated cobalt phosphate with a zeolite topology

Hong Ming Yuan^*, Jie Sheng Chen, Guang Shan Zhu, Ji Yang Li, Ji Hong Yu, Guang Di Yang, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)₃]Cl₃ and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H₃NCH₂CH₂NH₃)_0.5·CoPO₄) crystallizes in the monoclinic space group C2/c with a = 14.744(3) Å, b = 8.850(3) Å, c = 10.062(3) Å, β = 131.609(19)°, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO₄ and PO₄ tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO₄ framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology.

Original language	English
Pages (from-to)	1476-1479
Number of pages	4
Journal	Inorganic Chemistry
Volume	39
Issue number	7
DOIs	https://doi.org/10.1021/ic990719b
Publication status	Published - 3 Apr 2000
Externally published	Yes

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@article{759cfcec621f4725b5aa83c309dc538b,

title = "The first organo-templated cobalt phosphate with a zeolite topology",

abstract = "An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)3]Cl3 and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H3NCH2CH2NH3)0.5·CoPO4) crystallizes in the monoclinic space group C2/c with a = 14.744(3) {\AA}, b = 8.850(3) {\AA}, c = 10.062(3) {\AA}, β = 131.609(19)°, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO4 and PO4 tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO4 framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology.",

author = "Yuan, {Hong Ming} and Chen, {Jie Sheng} and Zhu, {Guang Shan} and Li, {Ji Yang} and Yu, {Ji Hong} and Yang, {Guang Di} and Xu, {Ru Ren}",

year = "2000",

month = apr,

day = "3",

doi = "10.1021/ic990719b",

language = "English",

volume = "39",

pages = "1476--1479",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

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TY - JOUR

T1 - The first organo-templated cobalt phosphate with a zeolite topology

AU - Yuan, Hong Ming

AU - Chen, Jie Sheng

AU - Zhu, Guang Shan

AU - Li, Ji Yang

AU - Yu, Ji Hong

AU - Yang, Guang Di

AU - Xu, Ru Ren

PY - 2000/4/3

Y1 - 2000/4/3

N2 - An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)3]Cl3 and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H3NCH2CH2NH3)0.5·CoPO4) crystallizes in the monoclinic space group C2/c with a = 14.744(3) Å, b = 8.850(3) Å, c = 10.062(3) Å, β = 131.609(19)°, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO4 and PO4 tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO4 framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology.

AB - An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)3]Cl3 and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H3NCH2CH2NH3)0.5·CoPO4) crystallizes in the monoclinic space group C2/c with a = 14.744(3) Å, b = 8.850(3) Å, c = 10.062(3) Å, β = 131.609(19)°, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO4 and PO4 tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO4 framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology.

UR - http://www.scopus.com/inward/record.url?scp=0034599314&partnerID=8YFLogxK

U2 - 10.1021/ic990719b

DO - 10.1021/ic990719b

M3 - Article

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AN - SCOPUS:0034599314

SN - 0020-1669

VL - 39

SP - 1476

EP - 1479

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

The first organo-templated cobalt phosphate with a zeolite topology

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