TY - JOUR
T1 - Synthetic mechanism for 1,3,5-triacetyl-1,3,5-triazacyclohexane synthesized using small-molecule method
AU - Lou, Zhongliang
AU - Wang, Peng
AU - Meng, Zihui
AU - Liu, Yue
AU - Qin, Guangming
AU - Ge, Zhongxue
AU - Wang, Bozhou
PY - 2010/7
Y1 - 2010/7
N2 - 1,3,5-Triacetyl-1,3,5-triazacyclohexane (TRAT) is the key synthetic precursor for hexahydro-1,3,5-trinitro-s-triazine (RDX). TRAT was synthesized from 1,3,5-trioxane with acetonitrile using concentrated sulfuric acid as a catalyst with a yield of 89% by an improved method. The stable intermediates, methylene-bis-alkanecarboxamide and triacetyl-bismethylene-triamine never reported were synthesized. According to intermediates synthesized, synthetic mechanism for TRAT from small molecules was proposed.
AB - 1,3,5-Triacetyl-1,3,5-triazacyclohexane (TRAT) is the key synthetic precursor for hexahydro-1,3,5-trinitro-s-triazine (RDX). TRAT was synthesized from 1,3,5-trioxane with acetonitrile using concentrated sulfuric acid as a catalyst with a yield of 89% by an improved method. The stable intermediates, methylene-bis-alkanecarboxamide and triacetyl-bismethylene-triamine never reported were synthesized. According to intermediates synthesized, synthetic mechanism for TRAT from small molecules was proposed.
KW - 1-3-5-triacetyl-1-3-5-triazacyclohexane
KW - Hexogen
KW - Reaction mechanism
UR - http://www.scopus.com/inward/record.url?scp=78349284707&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:78349284707
SN - 0253-2786
VL - 30
SP - 1059
EP - 1062
JO - Chinese Journal of Organic Chemistry
JF - Chinese Journal of Organic Chemistry
IS - 7
ER -