Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang; H. Li; G. Liu; T. T. Liu; F. Yue; J. D. Wang

doi:10.1134/S1070328411060121

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

H. Y. Zhang, H. Li, G. Liu, T. T. Liu, F. Yue^*, J. D. Wang

^*Corresponding author for this work

Xinjiang University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

One-pot reaction containing Zn(NO₃)₂, Cd(NO ₃)₂, NH₄SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)₂(SCN)₂] _n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd_2.84Zn_2.16(Atrz)₆(SCN)₁₀] • 4H₂O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

Original language	English
Pages (from-to)	411-416
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	37
Issue number	6
DOIs	https://doi.org/10.1134/S1070328411060121
Publication status	Published - Jun 2011
Externally published	Yes

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Zhang, H. Y., Li, H., Liu, G., Liu, T. T., Yue, F., & Wang, J. D. (2011). Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 37(6), 411-416. https://doi.org/10.1134/S1070328411060121

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title = "Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time",

abstract = "One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..",

author = "Zhang, {H. Y.} and H. Li and G. Liu and Liu, {T. T.} and F. Yue and Wang, {J. D.}",

year = "2011",

month = jun,

doi = "10.1134/S1070328411060121",

language = "English",

volume = "37",

pages = "411--416",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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T1 - Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

AU - Zhang, H. Y.

AU - Li, H.

AU - Liu, G.

AU - Liu, T. T.

AU - Yue, F.

AU - Wang, J. D.

PY - 2011/6

Y1 - 2011/6

N2 - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

AB - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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IS - 6

ER -

Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time

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