TY - JOUR
T1 - Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time
AU - Zhang, H. Y.
AU - Li, H.
AU - Liu, G.
AU - Liu, T. T.
AU - Yue, F.
AU - Wang, J. D.
PY - 2011/6
Y1 - 2011/6
N2 - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..
AB - One-pot reaction containing Zn(NO3)2, Cd(NO 3)2, NH4SCN, and 4-amino-1,2,4-triazole (Atrz) was proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz)2(SCN)2] n . However, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd2.84Zn2.16(Atrz)6(SCN)10] • 4H2O (I) with 66 topology was obtained. The photoluminescence property of I in the solid state was discussed..
UR - http://www.scopus.com/inward/record.url?scp=79960069334&partnerID=8YFLogxK
U2 - 10.1134/S1070328411060121
DO - 10.1134/S1070328411060121
M3 - Article
AN - SCOPUS:79960069334
SN - 1070-3284
VL - 37
SP - 411
EP - 416
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
IS - 6
ER -