Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)

Lin Jun Xue; Zhan Tang; Yan Gang Bi; Jing Jing Rong; Li Yang; Tong Lai Zhang

doi:10.11943/j.issn.1006-9941.2015.05.003

Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)

Lin Jun Xue, Zhan Tang, Yan Gang Bi, Jing Jing Rong, Li Yang^*, Tong Lai Zhang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Sodium dichloroisocyanurate was replaced by sodium hypochlorite as the oxidant for improving the synthetic method of 4, 4'-azobis (1, 2, 4-triazole). Three different factors, the illumination time, the molar ratio available chlorine to acetic acid and the reaction temperature, were studied for the influence of the reaction process. The structure and properties of the product obtained were compared with literature ones. Results show that under the condition of dark (0h illumination time), the molar ratio available chlorine to acetic acid 1: 2.5 and 7℃, the yield is 78%. Compared with sodium dichloroisocyanurate, sodium hypochlorite used as the oxidizing agent to synthesize 4, 4'-azobis(1, 2, 4-triazole) can not only omit the separation and purification of 4, 4'-azobis(1, 2, 4-triazole), but also solve the problem of processing the isocyanuric acid.

Original language	English
Pages (from-to)	420-423
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	23
Issue number	5
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2015.05.003
Publication status	Published - 25 May 2015

Keywords

4, 4'-azobis(1, 2, 4-triazole)
4-amino-1, 2, 4-triazole
Sodium dichloroisocyanurate
Sodium hypochlorite
The synthetic method

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10.11943/j.issn.1006-9941.2015.05.003

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@article{b044e3993acd473e871388308aba448e,

title = "Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)",

abstract = "Sodium dichloroisocyanurate was replaced by sodium hypochlorite as the oxidant for improving the synthetic method of 4, 4'-azobis (1, 2, 4-triazole). Three different factors, the illumination time, the molar ratio available chlorine to acetic acid and the reaction temperature, were studied for the influence of the reaction process. The structure and properties of the product obtained were compared with literature ones. Results show that under the condition of dark (0h illumination time), the molar ratio available chlorine to acetic acid 1: 2.5 and 7℃, the yield is 78%. Compared with sodium dichloroisocyanurate, sodium hypochlorite used as the oxidizing agent to synthesize 4, 4'-azobis(1, 2, 4-triazole) can not only omit the separation and purification of 4, 4'-azobis(1, 2, 4-triazole), but also solve the problem of processing the isocyanuric acid.",

keywords = "4, 4'-azobis(1, 2, 4-triazole), 4-amino-1, 2, 4-triazole, Sodium dichloroisocyanurate, Sodium hypochlorite, The synthetic method",

author = "Xue, {Lin Jun} and Zhan Tang and Bi, {Yan Gang} and Rong, {Jing Jing} and Li Yang and Zhang, {Tong Lai}",

year = "2015",

month = may,

day = "25",

doi = "10.11943/j.issn.1006-9941.2015.05.003",

language = "English",

volume = "23",

pages = "420--423",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Chinese Academy of Engineering Physics",

number = "5",

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TY - JOUR

T1 - Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)

AU - Xue, Lin Jun

AU - Tang, Zhan

AU - Bi, Yan Gang

AU - Rong, Jing Jing

AU - Yang, Li

AU - Zhang, Tong Lai

PY - 2015/5/25

Y1 - 2015/5/25

N2 - Sodium dichloroisocyanurate was replaced by sodium hypochlorite as the oxidant for improving the synthetic method of 4, 4'-azobis (1, 2, 4-triazole). Three different factors, the illumination time, the molar ratio available chlorine to acetic acid and the reaction temperature, were studied for the influence of the reaction process. The structure and properties of the product obtained were compared with literature ones. Results show that under the condition of dark (0h illumination time), the molar ratio available chlorine to acetic acid 1: 2.5 and 7℃, the yield is 78%. Compared with sodium dichloroisocyanurate, sodium hypochlorite used as the oxidizing agent to synthesize 4, 4'-azobis(1, 2, 4-triazole) can not only omit the separation and purification of 4, 4'-azobis(1, 2, 4-triazole), but also solve the problem of processing the isocyanuric acid.

AB - Sodium dichloroisocyanurate was replaced by sodium hypochlorite as the oxidant for improving the synthetic method of 4, 4'-azobis (1, 2, 4-triazole). Three different factors, the illumination time, the molar ratio available chlorine to acetic acid and the reaction temperature, were studied for the influence of the reaction process. The structure and properties of the product obtained were compared with literature ones. Results show that under the condition of dark (0h illumination time), the molar ratio available chlorine to acetic acid 1: 2.5 and 7℃, the yield is 78%. Compared with sodium dichloroisocyanurate, sodium hypochlorite used as the oxidizing agent to synthesize 4, 4'-azobis(1, 2, 4-triazole) can not only omit the separation and purification of 4, 4'-azobis(1, 2, 4-triazole), but also solve the problem of processing the isocyanuric acid.

KW - 4, 4'-azobis(1, 2, 4-triazole)

KW - 4-amino-1, 2, 4-triazole

KW - Sodium dichloroisocyanurate

KW - Sodium hypochlorite

KW - The synthetic method

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U2 - 10.11943/j.issn.1006-9941.2015.05.003

DO - 10.11943/j.issn.1006-9941.2015.05.003

M3 - Article

AN - SCOPUS:84930332040

SN - 1006-9941

VL - 23

SP - 420

EP - 423

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 5

ER -

Synthesis improvement for 4, 4'-azobis (1, 2, 4-triazole)

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Keywords

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