Abstract
The oxalate-bridged Schiff-based complex {[FeIII(salapn)]2(C2O4)} (1) has been synthesized and characterized structurally (salapn = N,N′-bis(salicylaldehyde)-1,3-diaminopentane dianion). Each iron(III) ion is coordinated in slightly distorted octahedral geometry by two oxygen atoms and two nitrogen atoms from a salapn ligand, and two carboxylate oxygen atoms from an oxalate ligand. The [Fe(salapn)] moiety is linked by a bridging oxalate ligand to form a dimeric entity. The magnetic susceptibility study of 1 demonstrates the presence of antiferromagnetic interaction between two Fe(III) ions.
Original language | English |
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Pages (from-to) | 49-52 |
Number of pages | 4 |
Journal | Journal of Molecular Structure |
Volume | 833 |
Issue number | 1-3 |
DOIs | |
Publication status | Published - 15 May 2007 |
Externally published | Yes |
Keywords
- Bridging oxalate
- Crystal structure
- Diiron(III) complex
- Magnetic properties
- Schiff-base
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Jia, H. P., Li, W., Ju, Z. F., & Zhang, J. (2007). Synthesis, crystal structure and magnetic properties of an oxalate-bridged diiron(III) complex {[FeIII(salapn)]2(C2O4)}. Journal of Molecular Structure, 833(1-3), 49-52. https://doi.org/10.1016/j.molstruc.2006.09.003