Synthesis and structural characterisation of a new layered aluminophosphate[C3H12N2][Al2P 2O8(OH)2]·H2O

Hong Ming Yuan; Jie Sheng Chen; Zhan Shi; Wei Chen; Ying Wang; Ping Zhang; Ji Hong Yu; Ru Ren Xu

doi:10.1039/b000685h

Synthesis and structural characterisation of a new layered aluminophosphate[C₃H₁₂N₂][Al₂P ₂O₈(OH)₂]·H₂O

Hong Ming Yuan^*, Jie Sheng Chen, Zhan Shi, Wei Chen, Ying Wang, Ping Zhang, Ji Hong Yu, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A new layered aluminophosphate [C₃H₁₂N₂][Al₂P₂O ₈(OH)₂]·H₂O has been synthesized hydrothermally by using racemic 1,2-diaminopropane as the structure-directing agent. Its structure, solved by single-crystal X-ray diffraction analysis, consists of [Al₂P₂O₈(OH)₂]^2- macroanionic sheets stacked in an ABAB sequence, and diprotonated racemic 1,2-diaminopropane cations lying between the inorganic sheets. Hydrogen bonds exist between the oxygen atoms in the sheets and nitrogen atoms of the diprotonated 1,2-diaminopropane molecules. The as-synthesized product has also been characterised by powder X-ray diffraction, inductive coupled plasma analysis, IR spectroscopy, TGA and DTA.

Original language	English
Pages (from-to)	1981-1984
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/b000685h
Publication status	Published - 2000
Externally published	Yes

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title = "Synthesis and structural characterisation of a new layered aluminophosphate[C3H12N2][Al2P 2O8(OH)2]·H2O",

abstract = "A new layered aluminophosphate [C3H12N2][Al2P2O 8(OH)2]·H2O has been synthesized hydrothermally by using racemic 1,2-diaminopropane as the structure-directing agent. Its structure, solved by single-crystal X-ray diffraction analysis, consists of [Al2P2O8(OH)2]2- macroanionic sheets stacked in an ABAB sequence, and diprotonated racemic 1,2-diaminopropane cations lying between the inorganic sheets. Hydrogen bonds exist between the oxygen atoms in the sheets and nitrogen atoms of the diprotonated 1,2-diaminopropane molecules. The as-synthesized product has also been characterised by powder X-ray diffraction, inductive coupled plasma analysis, IR spectroscopy, TGA and DTA.",

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T1 - Synthesis and structural characterisation of a new layered aluminophosphate[C3H12N2][Al2P 2O8(OH)2]·H2O

AU - Yuan, Hong Ming

AU - Chen, Jie Sheng

AU - Shi, Zhan

AU - Chen, Wei

AU - Wang, Ying

AU - Zhang, Ping

AU - Yu, Ji Hong

AU - Xu, Ru Ren

PY - 2000

Y1 - 2000

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AB - A new layered aluminophosphate [C3H12N2][Al2P2O 8(OH)2]·H2O has been synthesized hydrothermally by using racemic 1,2-diaminopropane as the structure-directing agent. Its structure, solved by single-crystal X-ray diffraction analysis, consists of [Al2P2O8(OH)2]2- macroanionic sheets stacked in an ABAB sequence, and diprotonated racemic 1,2-diaminopropane cations lying between the inorganic sheets. Hydrogen bonds exist between the oxygen atoms in the sheets and nitrogen atoms of the diprotonated 1,2-diaminopropane molecules. The as-synthesized product has also been characterised by powder X-ray diffraction, inductive coupled plasma analysis, IR spectroscopy, TGA and DTA.

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SN - 1470-479X

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JO - Journal of the Chemical Society. Dalton Transactions

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IS - 13

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Synthesis and structural characterisation of a new layered aluminophosphate[C₃H₁₂N₂][Al₂P ₂O₈(OH)₂]·H₂O

Abstract

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