Synthesis and structural characterisation of a new layered aluminophosphate[C3H12N2][Al2P 2O8(OH)2]·H2O

Hong Ming Yuan*, Jie Sheng Chen, Zhan Shi, Wei Chen, Ying Wang, Ping Zhang, Ji Hong Yu, Ru Ren Xu

*Corresponding author for this work

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Abstract

A new layered aluminophosphate [C3H12N2][Al2P2O 8(OH)2]·H2O has been synthesized hydrothermally by using racemic 1,2-diaminopropane as the structure-directing agent. Its structure, solved by single-crystal X-ray diffraction analysis, consists of [Al2P2O8(OH)2]2- macroanionic sheets stacked in an ABAB sequence, and diprotonated racemic 1,2-diaminopropane cations lying between the inorganic sheets. Hydrogen bonds exist between the oxygen atoms in the sheets and nitrogen atoms of the diprotonated 1,2-diaminopropane molecules. The as-synthesized product has also been characterised by powder X-ray diffraction, inductive coupled plasma analysis, IR spectroscopy, TGA and DTA.

Original languageEnglish
Pages (from-to)1981-1984
Number of pages4
JournalJournal of the Chemical Society. Dalton Transactions
Issue number13
DOIs
Publication statusPublished - 2000
Externally publishedYes

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Yuan, H. M., Chen, J. S., Shi, Z., Chen, W., Wang, Y., Zhang, P., Yu, J. H., & Xu, R. R. (2000). Synthesis and structural characterisation of a new layered aluminophosphate[C3H12N2][Al2P 2O8(OH)2]·H2O. Journal of the Chemical Society. Dalton Transactions, (13), 1981-1984. https://doi.org/10.1039/b000685h