Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer

Lan Fen Chen; Jie Zhang; Li Jun Song; Zhan Feng Ju

doi:10.1016/j.inoche.2005.03.019

Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ₂-aqua)bis(μ₂- carboxylate)-bridged manganese polymer

Lan Fen Chen, Jie Zhang^*, Li Jun Song, Zhan Feng Ju

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A manganese coordination polymer [Mn₂(NTC)(H₂O) ₂]_n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H ₄NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

Original language	English
Pages (from-to)	555-558
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2005.03.019
Publication status	Published - Jun 2005
Externally published	Yes

Keywords

1,4,5,8-Naphthalenetetracarboxylate
Coordination polymer
Crystal structure
Magnetic
Manganese(II) complex

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10.1016/j.inoche.2005.03.019

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Chen, L. F., Zhang, J., Song, L. J., & Ju, Z. F. (2005). Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ₂-aqua)bis(μ₂- carboxylate)-bridged manganese polymer. Inorganic Chemistry Communications, 8(6), 555-558. https://doi.org/10.1016/j.inoche.2005.03.019

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title = "Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2- carboxylate)-bridged manganese polymer",

abstract = "A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.",

keywords = "1,4,5,8-Naphthalenetetracarboxylate, Coordination polymer, Crystal structure, Magnetic, Manganese(II) complex",

author = "Chen, {Lan Fen} and Jie Zhang and Song, {Li Jun} and Ju, {Zhan Feng}",

year = "2005",

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doi = "10.1016/j.inoche.2005.03.019",

language = "English",

volume = "8",

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AU - Chen, Lan Fen

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AU - Song, Li Jun

AU - Ju, Zhan Feng

PY - 2005/6

Y1 - 2005/6

N2 - A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

AB - A manganese coordination polymer [Mn2(NTC)(H2O) 2]n, where NTC is 1,4,5,8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H 4NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.

KW - 1,4,5,8-Naphthalenetetracarboxylate

KW - Coordination polymer

KW - Crystal structure

KW - Magnetic

KW - Manganese(II) complex

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SN - 1387-7003

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SP - 555

EP - 558

JO - Inorganic Chemistry Communications

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IS - 6

ER -

Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ₂-aqua)bis(μ₂- carboxylate)-bridged manganese polymer

Abstract

Keywords

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