Synthesis and characterization of a novel energetic complex [Cd(DAT) 6](NO3)2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content

Jian Guo Zhang; Jing Yu Li; Yan Zang; Yuan Jie Shu; Tong Lai Zhang; Li Yang; Philip P. Power

doi:10.1002/zaac.200900502

Synthesis and characterization of a novel energetic complex [Cd(DAT) ₆](NO₃)₂ (DAT = 1,5-diamino-tetrazole) with high nitrogen content

Jian Guo Zhang^*, Jing Yu Li, Yan Zang, Yuan Jie Shu, Tong Lai Zhang, Li Yang, Philip P. Power

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The novel high nitrogen-containing energetic complex [Cd(DAT) ₆](NO₃)₂was synthesized by reaction of Cd(NO₃)₂·6H₂O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd²⁺ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)₆](NO ₃)₂ molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)₆](NO₃) ₂ was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

Original language	English
Pages (from-to)	1147-1151
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	636
Issue number	6
DOIs	https://doi.org/10.1002/zaac.200900502
Publication status	Published - May 2010

Keywords

1-5-diamino-tetrazole (DAT)
Cadmium
Nitrogen
Structure elucidation
Thermochemistry

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10.1002/zaac.200900502

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Zhang, J. G., Li, J. Y., Zang, Y., Shu, Y. J., Zhang, T. L., Yang, L., & Power, P. P. (2010). Synthesis and characterization of a novel energetic complex [Cd(DAT) ₆](NO₃)₂ (DAT = 1,5-diamino-tetrazole) with high nitrogen content. Zeitschrift fur Anorganische und Allgemeine Chemie, 636(6), 1147-1151. https://doi.org/10.1002/zaac.200900502

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abstract = "The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.",

keywords = "1-5-diamino-tetrazole (DAT), Cadmium, Nitrogen, Structure elucidation, Thermochemistry",

author = "Zhang, {Jian Guo} and Li, {Jing Yu} and Yan Zang and Shu, {Yuan Jie} and Zhang, {Tong Lai} and Li Yang and Power, {Philip P.}",

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AU - Zhang, Jian Guo

AU - Li, Jing Yu

AU - Zang, Yan

AU - Shu, Yuan Jie

AU - Zhang, Tong Lai

AU - Yang, Li

AU - Power, Philip P.

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N2 - The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

AB - The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

KW - 1-5-diamino-tetrazole (DAT)

KW - Cadmium

KW - Nitrogen

KW - Structure elucidation

KW - Thermochemistry

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Synthesis and characterization of a novel energetic complex [Cd(DAT) ₆](NO₃)₂ (DAT = 1,5-diamino-tetrazole) with high nitrogen content

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