Abstract
Two 1-allyl-3-butylimidazolium ionic liquids were synthesized and polymerized in-column as stationary phases in capillary gas chromatography. The influences of different counter ions (hexafluorophosphate, tetrafluoroborate) were studied. The results indicated that 1-allyl-3-butyl-imidazolium ionic liquids possessed good column coating properties and chromatographic separation abilities after polymerized in-column. The Grobs mixture, alcohols and alkanes and aromatic position isomers, such as xylene, nitrotoluene, dichlorobenzene and cresol were separated well. These polymeric ionic liquids gave potential to separate some complex compounds including alcohol, amine, ester etc.
| Original language | English |
|---|---|
| Title of host publication | Application of Chemical Engineering |
| Pages | 2639-2642 |
| Number of pages | 4 |
| DOIs | |
| Publication status | Published - 2011 |
| Event | 2011 International Conference on Chemical Engineering and Advanced Materials, CEAM 2011 - Changsha, China Duration: 28 May 2011 → 30 May 2011 |
Publication series
| Name | Advanced Materials Research |
|---|---|
| Volume | 236-238 |
| ISSN (Print) | 1022-6680 |
Conference
| Conference | 2011 International Conference on Chemical Engineering and Advanced Materials, CEAM 2011 |
|---|---|
| Country/Territory | China |
| City | Changsha |
| Period | 28/05/11 → 30/05/11 |
Keywords
- Allyl-imidazolium
- Gas chromatography
- Ionic liquid
- Polymer stationary phase
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Zhang, L. X., Liu, T., Chen, Z. H., Sun, L. Q., & Luo, A. Q. (2011). Synthesis and application of poly-allyl-imidazolium ionic liquid stationary phase in capillary gas chromatography. In Application of Chemical Engineering (pp. 2639-2642). (Advanced Materials Research; Vol. 236-238). https://doi.org/10.4028/www.scientific.net/AMR.236-238.2639