Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

Jin Ting Wu; Jian Guo Zhang; Xin Jin; Xin Yin; Tong Lai Zhang

doi:10.1080/00958972.2016.1160378

Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

Jin Ting Wu, Jian Guo Zhang^*, Xin Jin, Xin Yin, Tong Lai Zhang

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two new ionic complexes, (DATr)₂[Li₂(TNR)₂·2H₂O]·2H₂O (1) and (DATr)[Zn(DATr)Cl₃] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

Original language	English
Pages (from-to)	1236-1243
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	69
Issue number	7
DOIs	https://doi.org/10.1080/00958972.2016.1160378
Publication status	Published - 2016

Keywords

3,4-diamino-1,2,4-triazole
Complexes
crystal structure
thermal analysis

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10.1080/00958972.2016.1160378

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title = "Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole",

abstract = "Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).",

keywords = "3,4-diamino-1,2,4-triazole, Complexes, crystal structure, thermal analysis",

author = "Wu, {Jin Ting} and Zhang, {Jian Guo} and Xin Jin and Xin Yin and Zhang, {Tong Lai}",

note = "Publisher Copyright: {\textcopyright} 2016 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2016",

doi = "10.1080/00958972.2016.1160378",

language = "English",

volume = "69",

pages = "1236--1243",

journal = "Journal of Coordination Chemistry",

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TY - JOUR

T1 - Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

AU - Wu, Jin Ting

AU - Zhang, Jian Guo

AU - Jin, Xin

AU - Yin, Xin

AU - Zhang, Tong Lai

PY - 2016

Y1 - 2016

N2 - Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

AB - Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

KW - 3,4-diamino-1,2,4-triazole

KW - Complexes

KW - crystal structure

KW - thermal analysis

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DO - 10.1080/00958972.2016.1160378

M3 - Article

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SN - 0095-8972

VL - 69

SP - 1236

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JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 7

ER -

Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

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Keywords

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