Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

Jin Ting Wu, Jian Guo Zhang*, Xin Jin, Xin Yin, Tong Lai Zhang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

Original languageEnglish
Pages (from-to)1236-1243
Number of pages8
JournalJournal of Coordination Chemistry
Volume69
Issue number7
DOIs
Publication statusPublished - 2016

Keywords

  • 3,4-diamino-1,2,4-triazole
  • Complexes
  • crystal structure
  • thermal analysis

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