Syntheses and molecular self-assembly of chiral phosphoramidates

Da Ming Du; Wen Ting Hua; Jian Wu Wang; Xiang Lin Jin

doi:10.1002/cjoc.20000180520

Syntheses and molecular self-assembly of chiral phosphoramidates

Da Ming Du, Wen Ting Hua, Jian Wu Wang, Xiang Lin Jin

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Two chiral phosphoramidates, (R)-(-)-1, 1′-binaphthyl-2, 2′-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1, 1′-biphenyl-2, 2′-dihydroxy-N-[α -(S)-methylbenzyl]-phosphoramidate were synthesized. Their crystal structures were determined by X-ray single crystal diffraction analysis. The phosphoramidate molecules are self-associated by intermolecular N - H···O = P hydrogen bonds and aromatic edge to face interactions.

Original language	English
Pages (from-to)	764-769
Number of pages	6
Journal	Chinese Journal of Chemistry
Volume	18
Issue number	5
DOIs	https://doi.org/10.1002/cjoc.20000180520
Publication status	Published - 1 Jan 2000
Externally published	Yes

Keywords

Crystal structure
Hydrogen bond
Phosphoramidate

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title = "Syntheses and molecular self-assembly of chiral phosphoramidates",

abstract = "Two chiral phosphoramidates, (R)-(-)-1, 1′-binaphthyl-2, 2′-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1, 1′-biphenyl-2, 2′-dihydroxy-N-[α -(S)-methylbenzyl]-phosphoramidate were synthesized. Their crystal structures were determined by X-ray single crystal diffraction analysis. The phosphoramidate molecules are self-associated by intermolecular N - H···O = P hydrogen bonds and aromatic edge to face interactions.",

keywords = "Crystal structure, Hydrogen bond, Phosphoramidate",

author = "Du, {Da Ming} and Hua, {Wen Ting} and Wang, {Jian Wu} and Jin, {Xiang Lin}",

year = "2000",

month = jan,

day = "1",

doi = "10.1002/cjoc.20000180520",

language = "English",

volume = "18",

pages = "764--769",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley & Sons Inc.",

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TY - JOUR

T1 - Syntheses and molecular self-assembly of chiral phosphoramidates

AU - Du, Da Ming

AU - Hua, Wen Ting

AU - Wang, Jian Wu

AU - Jin, Xiang Lin

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Two chiral phosphoramidates, (R)-(-)-1, 1′-binaphthyl-2, 2′-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1, 1′-biphenyl-2, 2′-dihydroxy-N-[α -(S)-methylbenzyl]-phosphoramidate were synthesized. Their crystal structures were determined by X-ray single crystal diffraction analysis. The phosphoramidate molecules are self-associated by intermolecular N - H···O = P hydrogen bonds and aromatic edge to face interactions.

AB - Two chiral phosphoramidates, (R)-(-)-1, 1′-binaphthyl-2, 2′-dihydroxy-N-[α-(S)-methylbenzyl] phosphoramidate and (-)-1, 1′-biphenyl-2, 2′-dihydroxy-N-[α -(S)-methylbenzyl]-phosphoramidate were synthesized. Their crystal structures were determined by X-ray single crystal diffraction analysis. The phosphoramidate molecules are self-associated by intermolecular N - H···O = P hydrogen bonds and aromatic edge to face interactions.

KW - Crystal structure

KW - Hydrogen bond

KW - Phosphoramidate

UR - http://www.scopus.com/inward/record.url?scp=0034450967&partnerID=8YFLogxK

U2 - 10.1002/cjoc.20000180520

DO - 10.1002/cjoc.20000180520

M3 - Article

AN - SCOPUS:0034450967

SN - 1001-604X

VL - 18

SP - 764

EP - 769

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 5

ER -

Syntheses and molecular self-assembly of chiral phosphoramidates

Abstract

Keywords

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