Studies on the structural transformation of one-dimensional aluminophosphate chains

Hong Ding; Kai Xue Wang; Ji Hong Yu; Chao Wang; Ru Ren Xu

Studies on the structural transformation of one-dimensional aluminophosphate chains

Hong Ding^*, Kai Xue Wang, Ji Hong Yu, Chao Wang, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

Abstract

In the Al(i-PRO)₃-H₃PO₄-en-EG system, two one-dimensional (1D) aluminophosphate chains AlPO-ESC and AlPO-CSC can transform to each other upon addition of some extra amount of en or H ₃PO₄ to the reaction mixture. The transformation process has been studied by XRD and compositional analyses. Introducing Ni²⁺ cations, the 1D AlPO-CSC chain which acts as BU can be successfully assembled to 3D open-framework NiAlP₂O₈·C₂N ₂H₉ (NiAPO-1) by connecting the terminal phosphonyl oxygens with Ni²⁺ species.

Original language	English
Pages (from-to)	69-72
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	1
Publication status	Published - 1 Jan 2003
Externally published	Yes

Keywords

Aluminophosphates
Open-framework
Rational synthesis
Structural transformation

Cite this

Ding, H., Wang, K. X., Yu, J. H., Wang, C., & Xu, R. R. (2003). Studies on the structural transformation of one-dimensional aluminophosphate chains. Chinese Journal of Inorganic Chemistry, 19(1), 69-72.

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title = "Studies on the structural transformation of one-dimensional aluminophosphate chains",

abstract = "In the Al(i-PRO)3-H3PO4-en-EG system, two one-dimensional (1D) aluminophosphate chains AlPO-ESC and AlPO-CSC can transform to each other upon addition of some extra amount of en or H 3PO4 to the reaction mixture. The transformation process has been studied by XRD and compositional analyses. Introducing Ni2+ cations, the 1D AlPO-CSC chain which acts as BU can be successfully assembled to 3D open-framework NiAlP2O8·C2N 2H9 (NiAPO-1) by connecting the terminal phosphonyl oxygens with Ni2+ species.",

keywords = "Aluminophosphates, Open-framework, Rational synthesis, Structural transformation",

author = "Hong Ding and Wang, {Kai Xue} and Yu, {Ji Hong} and Chao Wang and Xu, {Ru Ren}",

year = "2003",

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journal = "Chinese Journal of Inorganic Chemistry",

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T1 - Studies on the structural transformation of one-dimensional aluminophosphate chains

AU - Ding, Hong

AU - Wang, Kai Xue

AU - Yu, Ji Hong

AU - Wang, Chao

AU - Xu, Ru Ren

PY - 2003/1/1

Y1 - 2003/1/1

N2 - In the Al(i-PRO)3-H3PO4-en-EG system, two one-dimensional (1D) aluminophosphate chains AlPO-ESC and AlPO-CSC can transform to each other upon addition of some extra amount of en or H 3PO4 to the reaction mixture. The transformation process has been studied by XRD and compositional analyses. Introducing Ni2+ cations, the 1D AlPO-CSC chain which acts as BU can be successfully assembled to 3D open-framework NiAlP2O8·C2N 2H9 (NiAPO-1) by connecting the terminal phosphonyl oxygens with Ni2+ species.

AB - In the Al(i-PRO)3-H3PO4-en-EG system, two one-dimensional (1D) aluminophosphate chains AlPO-ESC and AlPO-CSC can transform to each other upon addition of some extra amount of en or H 3PO4 to the reaction mixture. The transformation process has been studied by XRD and compositional analyses. Introducing Ni2+ cations, the 1D AlPO-CSC chain which acts as BU can be successfully assembled to 3D open-framework NiAlP2O8·C2N 2H9 (NiAPO-1) by connecting the terminal phosphonyl oxygens with Ni2+ species.

KW - Aluminophosphates

KW - Open-framework

KW - Rational synthesis

KW - Structural transformation

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M3 - Article

AN - SCOPUS:0141463813

SN - 1001-4861

VL - 19

SP - 69

EP - 72

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

ER -

Studies on the structural transformation of one-dimensional aluminophosphate chains

Abstract

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