Stone-Wales defects in graphene and other planar s p2 -bonded materials

Jie Ma*, Dario Alfè, Angelos Michaelides, Enge Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

462 Citations (Scopus)

Abstract

Density functional theory and quantum Monte Carlo simulations reveal that the structure of the Stone-Wales (SW) defect in graphene is more complex than hitherto appreciated. Rather than being a simple in-plane transformation of two carbon atoms, out-of-plane wavelike defect structures that extend over several nanometers are predicted. Equivalent wavelike SW reconstructions are predicted for hexagonal boron-nitride and polycyclic aromatic hydrocarbons above a critical size, demonstrating the relevance of these predictions to s p2 -bonded materials in general.

Original languageEnglish
Article number033407
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume80
Issue number3
DOIs
Publication statusPublished - 6 Aug 2009
Externally publishedYes

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