Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

Ying Guo, Xiu Long Yang, Rong Jia Wei, Lan Sun Zheng, Jun Tao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

A mononuclear compound, [CoII(pyterpy)2](PF6)2·2CH3OH [2; pyterpy = 4′-(4⌄-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2](PF6)2·2CH2Cl2·CH3OH (3).

Original languageEnglish
Pages (from-to)7670-7672
Number of pages3
JournalInorganic Chemistry
Volume54
Issue number16
DOIs
Publication statusPublished - 17 Aug 2015
Externally publishedYes

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