TY - JOUR
T1 - Solvothermal synthesis and characterization of a new titanium phosphate with a one-dimensional chiral chain
AU - Guo, Y.
AU - Shi, Z.
AU - Yu, J.
AU - Wang, J.
AU - Liu, Y.
AU - Bai, N.
AU - Pang, W.
PY - 2001
Y1 - 2001
N2 - A new titanium phosphate, [Ti3P6O27]·5[NH3 CH2CH2NH3]·2[H3O], denoted JTP-A (Jilintitanium phosphate-A), has been synthesized under solvothermal conditions and its structure determined by single-crystal X-ray diffraction. It crystallizes in an enantiomorphic space group P212121 with lattice parameters a = 10.1800(6) Å, b = 15.8992(9) Å, c = 23.2271(12) Å, V = 3759(4) Å3, and Z = 4. The structure consists of one-dimensional chiral chains built up from corner-sharing titanium oxo octahedra running along the 21-screw axis, with the adjacent titanium oxo octahedra being bridged by phosphate tetrehedra. The Ti - O bond lengths along the backbone of the chain are alternately short and long. The results of TGA, IR, 31P MAS NMR, and second harmonics generation measurements are also presented.
AB - A new titanium phosphate, [Ti3P6O27]·5[NH3 CH2CH2NH3]·2[H3O], denoted JTP-A (Jilintitanium phosphate-A), has been synthesized under solvothermal conditions and its structure determined by single-crystal X-ray diffraction. It crystallizes in an enantiomorphic space group P212121 with lattice parameters a = 10.1800(6) Å, b = 15.8992(9) Å, c = 23.2271(12) Å, V = 3759(4) Å3, and Z = 4. The structure consists of one-dimensional chiral chains built up from corner-sharing titanium oxo octahedra running along the 21-screw axis, with the adjacent titanium oxo octahedra being bridged by phosphate tetrehedra. The Ti - O bond lengths along the backbone of the chain are alternately short and long. The results of TGA, IR, 31P MAS NMR, and second harmonics generation measurements are also presented.
UR - http://www.scopus.com/inward/record.url?scp=0035114827&partnerID=8YFLogxK
U2 - 10.1021/cm000642l
DO - 10.1021/cm000642l
M3 - Article
AN - SCOPUS:0035114827
SN - 0897-4756
VL - 13
SP - 203
EP - 207
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 1
ER -