Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode

Xuanlin Kuang; Xia Liu; Sixing Xu; Xiaohong Wang

doi:10.1109/TRANSDUCERS.2017.7994148

Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode

Xuanlin Kuang, Xia Liu, Sixing Xu, Xiaohong Wang^*

^*Corresponding author for this work

Tsinghua University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Citations (Scopus)

Abstract

We report a novel rGO/CNT/Si shell-like anode by using the vacuum filtration method, for lithium-ion batteries. The high-capacity silicon nanoparticles (SiNPs) are enclosed by a scaffold consisting of the stacked rGO shells and the CNT frame. The scaffold provides enough space for volume expansion of the SiNPs during the process of lithium-ion intercalation. The solid electrolyte interface (SEI) film forms on the surface of rGO shells, which can prevent electrolysis from consuming the silicon continuously. The anode demonstrates to enjoy the high specific capacity of 2372.77 mAh/g in initial cycle, and the superior recyclability with 1438.31 mAh/g after 100 cycles in a half-cell electrochemical test.

Original language	English
Title of host publication	TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	714-717
Number of pages	4
ISBN (Electronic)	9781538627310
DOIs	https://doi.org/10.1109/TRANSDUCERS.2017.7994148
Publication status	Published - 26 Jul 2017
Externally published	Yes
Event	19th International Conference on Solid-State Sensors, Actuators and Microsystems, TRANSDUCERS 2017 - Kaohsiung, Taiwan, Province of China Duration: 18 Jun 2017 → 22 Jun 2017

Publication series

Name	TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems

Conference

Conference	19th International Conference on Solid-State Sensors, Actuators and Microsystems, TRANSDUCERS 2017
Country/Territory	Taiwan, Province of China
City	Kaohsiung
Period	18/06/17 → 22/06/17

Keywords

Lithium-ion battery
Shell-like structure
Si anodes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1109/TRANSDUCERS.2017.7994148

Cite this

Kuang, X., Liu, X., Xu, S., & Wang, X. (2017). Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode. In TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems (pp. 714-717). Article 7994148 (TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/TRANSDUCERS.2017.7994148

Kuang, Xuanlin ; Liu, Xia ; Xu, Sixing et al. / Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode. TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems. Institute of Electrical and Electronics Engineers Inc., 2017. pp. 714-717 (TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems).

@inproceedings{79d3998c121f4ad5aafa8c0410a88219,

title = "Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode",

abstract = "We report a novel rGO/CNT/Si shell-like anode by using the vacuum filtration method, for lithium-ion batteries. The high-capacity silicon nanoparticles (SiNPs) are enclosed by a scaffold consisting of the stacked rGO shells and the CNT frame. The scaffold provides enough space for volume expansion of the SiNPs during the process of lithium-ion intercalation. The solid electrolyte interface (SEI) film forms on the surface of rGO shells, which can prevent electrolysis from consuming the silicon continuously. The anode demonstrates to enjoy the high specific capacity of 2372.77 mAh/g in initial cycle, and the superior recyclability with 1438.31 mAh/g after 100 cycles in a half-cell electrochemical test.",

keywords = "Lithium-ion battery, Shell-like structure, Si anodes",

author = "Xuanlin Kuang and Xia Liu and Sixing Xu and Xiaohong Wang",

note = "Publisher Copyright: {\textcopyright} 2017 IEEE.; 19th International Conference on Solid-State Sensors, Actuators and Microsystems, TRANSDUCERS 2017 ; Conference date: 18-06-2017 Through 22-06-2017",

year = "2017",

month = jul,

day = "26",

doi = "10.1109/TRANSDUCERS.2017.7994148",

language = "English",

series = "TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems",

publisher = "Institute of Electrical and Electronics Engineers Inc.",

pages = "714--717",

booktitle = "TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems",

address = "United States",

}

Kuang, X, Liu, X, Xu, S & Wang, X 2017, Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode. in TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems., 7994148, TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems, Institute of Electrical and Electronics Engineers Inc., pp. 714-717, 19th International Conference on Solid-State Sensors, Actuators and Microsystems, TRANSDUCERS 2017, Kaohsiung, Taiwan, Province of China, 18/06/17. https://doi.org/10.1109/TRANSDUCERS.2017.7994148

Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode. / Kuang, Xuanlin; Liu, Xia; Xu, Sixing et al.
TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems. Institute of Electrical and Electronics Engineers Inc., 2017. p. 714-717 7994148 (TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode

AU - Kuang, Xuanlin

AU - Liu, Xia

AU - Xu, Sixing

AU - Wang, Xiaohong

PY - 2017/7/26

Y1 - 2017/7/26

N2 - We report a novel rGO/CNT/Si shell-like anode by using the vacuum filtration method, for lithium-ion batteries. The high-capacity silicon nanoparticles (SiNPs) are enclosed by a scaffold consisting of the stacked rGO shells and the CNT frame. The scaffold provides enough space for volume expansion of the SiNPs during the process of lithium-ion intercalation. The solid electrolyte interface (SEI) film forms on the surface of rGO shells, which can prevent electrolysis from consuming the silicon continuously. The anode demonstrates to enjoy the high specific capacity of 2372.77 mAh/g in initial cycle, and the superior recyclability with 1438.31 mAh/g after 100 cycles in a half-cell electrochemical test.

AB - We report a novel rGO/CNT/Si shell-like anode by using the vacuum filtration method, for lithium-ion batteries. The high-capacity silicon nanoparticles (SiNPs) are enclosed by a scaffold consisting of the stacked rGO shells and the CNT frame. The scaffold provides enough space for volume expansion of the SiNPs during the process of lithium-ion intercalation. The solid electrolyte interface (SEI) film forms on the surface of rGO shells, which can prevent electrolysis from consuming the silicon continuously. The anode demonstrates to enjoy the high specific capacity of 2372.77 mAh/g in initial cycle, and the superior recyclability with 1438.31 mAh/g after 100 cycles in a half-cell electrochemical test.

KW - Lithium-ion battery

KW - Shell-like structure

KW - Si anodes

UR - http://www.scopus.com/inward/record.url?scp=85029351725&partnerID=8YFLogxK

U2 - 10.1109/TRANSDUCERS.2017.7994148

DO - 10.1109/TRANSDUCERS.2017.7994148

M3 - Conference contribution

AN - SCOPUS:85029351725

T3 - TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems

SP - 714

EP - 717

BT - TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems

PB - Institute of Electrical and Electronics Engineers Inc.

T2 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems, TRANSDUCERS 2017

Y2 - 18 June 2017 through 22 June 2017

ER -

Kuang X, Liu X, Xu S, Wang X. Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode. In TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems. Institute of Electrical and Electronics Engineers Inc. 2017. p. 714-717. 7994148. (TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems). doi: 10.1109/TRANSDUCERS.2017.7994148

Silicon enclosed in rGO/CNT shell-like scaffold as a micro lithium-ion battery anode

Abstract

Publication series

Conference

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this