Semi-Embedded Structured Bi Nanospheres for Boosted Self-Heating-Induced Healing of Li-Dendrites

It is reported that self-heating-induced healing on lithium metal anodes (LMAs) provides a mitigation strategy for suppressing Li dendrites. However, how to boost the self-heating-induced healing of Li-dendrites and incorporate it into Li-host design remains an imminent problem that needs to be solved. Herein, a new bismuth nanosphere semi-buried carbon cloth (Bi-NS-CC) material with a 3D flexible host structure is proposed. The ultrasmall Bi nanospheres are uniformly and densely distributed on carbon fiber, providing active sites to form uniform Li₃Bi alloy with molten lithium, thereby guiding the injection of molten metallic lithium into the 3D structure to form a self-supporting composite LMAs. The ingenious semi-embedded structure with strong interfacial C─Bi ensures superior mechanical properties. Interestingly, when the current density reaches up to 10 mA cm⁻², the lithium dendrites undergo self-heating. Carbon cloth as a host can quickly and uniformly transfer heat, which induces the uniform migration of Li on anodes. The semi-embedded structure with strong C─Bi ensures Bi nanospheres guide the formation of smooth morphology even under these harsh conditions (high-temperature, high-rate, etc.). Consequently, at 10 mA cm⁻²/10 mAh cm⁻², the Li/Li₃Bi-NS-CC realizes ultra-long cycles of 1500 h and ultra-low overpotential of 15 mV in a symmetric cell.