Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer

Xiaobang Zhang; Xiaomei Wei; Sheng Li Huang; Guo Yu Yang

doi:10.1002/asia.202100482

Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)₃ photosensitizer

Xiaobang Zhang, Xiaomei Wei, Sheng Li Huang^*, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)₃ photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

Original language	English
Pages (from-to)	2031-2034
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	16
Issue number	15
DOIs	https://doi.org/10.1002/asia.202100482
Publication status	Published - 2 Aug 2021

Keywords

Rare-earth metal-organic frameworks
Ru(N^N) photosensitizer
photocatalysis
sulfide oxidation

Access to Document

10.1002/asia.202100482

Cite this

@article{771600c33fa642839a51b5919735c3c8,

title = "Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer",

abstract = "Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.",

keywords = "Rare-earth metal-organic frameworks, Ru(N^N) photosensitizer, photocatalysis, sulfide oxidation",

author = "Xiaobang Zhang and Xiaomei Wei and Huang, {Sheng Li} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2021",

month = aug,

day = "2",

doi = "10.1002/asia.202100482",

language = "English",

volume = "16",

pages = "2031--2034",

journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

number = "15",

}

TY - JOUR

T1 - Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer

AU - Zhang, Xiaobang

AU - Wei, Xiaomei

AU - Huang, Sheng Li

AU - Yang, Guo Yu

PY - 2021/8/2

Y1 - 2021/8/2

N2 - Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

AB - Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

KW - Rare-earth metal-organic frameworks

KW - Ru(N^N) photosensitizer

KW - photocatalysis

KW - sulfide oxidation

UR - http://www.scopus.com/inward/record.url?scp=85111921367&partnerID=8YFLogxK

U2 - 10.1002/asia.202100482

DO - 10.1002/asia.202100482

M3 - Article

C2 - 34180132

AN - SCOPUS:85111921367

SN - 1861-4728

VL - 16

SP - 2031

EP - 2034

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 15

ER -

Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)₃ photosensitizer

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this