Sandwich phosphate complexes of macrocyclic tris(urea) ligands and their rotation around the anion

Liguo Ji; Zaiwen Yang; Yanxia Zhao; Meng Sun; Liping Cao; Xiao Juan Yang; Yao Yu Wang; Biao Wu

doi:10.1039/c6cc03144g

Sandwich phosphate complexes of macrocyclic tris(urea) ligands and their rotation around the anion

Liguo Ji, Zaiwen Yang, Yanxia Zhao, Meng Sun, Liping Cao, Xiao Juan Yang, Yao Yu Wang, Biao Wu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Four heteroditopic macrocyclic ligands incorporating both anion coordination sites (tris-urea units) and a cation binding fragment (polyether) were designed for possible application in molecular devices. Sandwich-type phosphate complexes were formed, which display a reversible rotation around the anion upon protonation/deprotonation of phosphate and binding of the cation (Emim⁺).

Original language	English
Pages (from-to)	7310-7313
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	45
DOIs	https://doi.org/10.1039/c6cc03144g
Publication status	Published - 2016
Externally published	Yes

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Ji, L., Yang, Z., Zhao, Y., Sun, M., Cao, L., Yang, X. J., Wang, Y. Y., & Wu, B. (2016). Sandwich phosphate complexes of macrocyclic tris(urea) ligands and their rotation around the anion. Chemical Communications, 52(45), 7310-7313. https://doi.org/10.1039/c6cc03144g

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abstract = "Four heteroditopic macrocyclic ligands incorporating both anion coordination sites (tris-urea units) and a cation binding fragment (polyether) were designed for possible application in molecular devices. Sandwich-type phosphate complexes were formed, which display a reversible rotation around the anion upon protonation/deprotonation of phosphate and binding of the cation (Emim+).",

author = "Liguo Ji and Zaiwen Yang and Yanxia Zhao and Meng Sun and Liping Cao and Yang, \{Xiao Juan\} and Wang, \{Yao Yu\} and Biao Wu",

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AU - Ji, Liguo

AU - Yang, Zaiwen

AU - Zhao, Yanxia

AU - Sun, Meng

AU - Cao, Liping

AU - Yang, Xiao Juan

AU - Wang, Yao Yu

AU - Wu, Biao

PY - 2016

Y1 - 2016

N2 - Four heteroditopic macrocyclic ligands incorporating both anion coordination sites (tris-urea units) and a cation binding fragment (polyether) were designed for possible application in molecular devices. Sandwich-type phosphate complexes were formed, which display a reversible rotation around the anion upon protonation/deprotonation of phosphate and binding of the cation (Emim+).

AB - Four heteroditopic macrocyclic ligands incorporating both anion coordination sites (tris-urea units) and a cation binding fragment (polyether) were designed for possible application in molecular devices. Sandwich-type phosphate complexes were formed, which display a reversible rotation around the anion upon protonation/deprotonation of phosphate and binding of the cation (Emim+).

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U2 - 10.1039/c6cc03144g

DO - 10.1039/c6cc03144g

M3 - Article

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VL - 52

SP - 7310

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JO - Chemical Communications

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Sandwich phosphate complexes of macrocyclic tris(urea) ligands and their rotation around the anion

Abstract

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