Role of LaNiO3 in suppressing voltage decay of layered lithium-rich cathode materials

Feng Wu, Qing Li, Liying Bao, Yu Zheng, Yun Lu*, Yuefeng Su, Jing Wang, Shi Chen, Renjie Chen, Jun Tian

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

50 Citations (Scopus)

Abstract

Lithium-rich cathode materials possess poor cycle stability and severe voltage decay during cycling. The main reason is that they suffer severe structure transformation during (I) Li2MnO3 activation in the initial charge process accompanied with the release of O2 and the extraction of Li-ions from transition metal (TM) layer; (II) the migration of TM-ions (Mn4+, Ni2+) from TM layer to Li layer during cycling. Both of them accelerate phase transformation from the layered to LiNixMn2−xO4 (0 ≤ x ≤ 2) spinel structure. In order to solve this problem, LaNiO3 surface reorganization layer is proposed in this work. In the process of surface modification, the La salts are decomposed and then bond with Ni ions that diffused from the bulk of particles to the surface at high-temperature calcinations. Due to the strong La–O bond energy, there is less Li2O removed and less lithium vacancy formed in TM layer during every charge processes. In addition, the stable existing form of Ni3+ in material surface inhibits the migration of TM-ions from TM layer into Li layer. LaNiO3 surface can protect the electrode from the erosion by electrolyte, and effectively impede the electrode/electrolyte interface side reactions. Owing to the positive effects of LaNiO3 surface reorganization layer, the modified Li1.2Mn0.6Ni0.2O2 samples exhibit superior high capacity retention (more than 87.7% after 200 cycles) with a significantly decrease in voltage decay, which exhibit an improvement over the state of art.

Original languageEnglish
Pages (from-to)986-993
Number of pages8
JournalElectrochimica Acta
Volume260
DOIs
Publication statusPublished - 10 Jan 2018

Keywords

  • Cycle Stability
  • Li-rich Cathode material
  • Lithium-ion Batteries
  • Surface Reorganization
  • Voltage Decay

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