Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine: A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene

Ya Dong Lu; Yan Hua Wang; Zi Lin Jin

doi:10.1016/j.cclet.2010.04.013

Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine: A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene

Ya Dong Lu, Yan Hua Wang^*, Zi Lin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine (PETPP, P[C₆H₄-p-(OCH₂CH₂)_nOH]₃) combining double stabilization effects demonstrated high activity and good recyclability in aqueous biphasic hydrogenation of benzene. The value of turnover frequency (TOF) was 3333h^-1. Furthermore, the rhodium nanoparticle catalyst could be easily recycled for five times without loss in activity.

Original language	English
Pages (from-to)	1067-1070
Number of pages	4
Journal	Chinese Chemical Letters
Volume	21
Issue number	9
DOIs	https://doi.org/10.1016/j.cclet.2010.04.013
Publication status	Published - Sept 2010
Externally published	Yes

Keywords

Aqueous biphasic catalysis
Hydrogenation
Nanoparticles
PETPP
Rhodium

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10.1016/j.cclet.2010.04.013

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title = "Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine: A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene",

abstract = "Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine (PETPP, P[C6H4-p-(OCH2CH2)nOH]3) combining double stabilization effects demonstrated high activity and good recyclability in aqueous biphasic hydrogenation of benzene. The value of turnover frequency (TOF) was 3333h-1. Furthermore, the rhodium nanoparticle catalyst could be easily recycled for five times without loss in activity.",

keywords = "Aqueous biphasic catalysis, Hydrogenation, Nanoparticles, PETPP, Rhodium",

author = "Lu, {Ya Dong} and Wang, {Yan Hua} and Jin, {Zi Lin}",

year = "2010",

month = sep,

doi = "10.1016/j.cclet.2010.04.013",

language = "English",

volume = "21",

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journal = "Chinese Chemical Letters",

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T1 - Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine

T2 - A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene

AU - Lu, Ya Dong

AU - Wang, Yan Hua

AU - Jin, Zi Lin

PY - 2010/9

Y1 - 2010/9

N2 - Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine (PETPP, P[C6H4-p-(OCH2CH2)nOH]3) combining double stabilization effects demonstrated high activity and good recyclability in aqueous biphasic hydrogenation of benzene. The value of turnover frequency (TOF) was 3333h-1. Furthermore, the rhodium nanoparticle catalyst could be easily recycled for five times without loss in activity.

AB - Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine (PETPP, P[C6H4-p-(OCH2CH2)nOH]3) combining double stabilization effects demonstrated high activity and good recyclability in aqueous biphasic hydrogenation of benzene. The value of turnover frequency (TOF) was 3333h-1. Furthermore, the rhodium nanoparticle catalyst could be easily recycled for five times without loss in activity.

KW - Aqueous biphasic catalysis

KW - Hydrogenation

KW - Nanoparticles

KW - PETPP

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=77955057982&partnerID=8YFLogxK

U2 - 10.1016/j.cclet.2010.04.013

DO - 10.1016/j.cclet.2010.04.013

M3 - Article

AN - SCOPUS:77955057982

SN - 1001-8417

VL - 21

SP - 1067

EP - 1070

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 9

ER -

Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine: A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene

Abstract

Keywords

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