Abstract
Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine (PETPP, P[C6H4-p-(OCH2CH2)nOH]3) combining double stabilization effects demonstrated high activity and good recyclability in aqueous biphasic hydrogenation of benzene. The value of turnover frequency (TOF) was 3333h-1. Furthermore, the rhodium nanoparticle catalyst could be easily recycled for five times without loss in activity.
Original language | English |
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Pages (from-to) | 1067-1070 |
Number of pages | 4 |
Journal | Chinese Chemical Letters |
Volume | 21 |
Issue number | 9 |
DOIs | |
Publication status | Published - Sept 2010 |
Externally published | Yes |
Keywords
- Aqueous biphasic catalysis
- Hydrogenation
- Nanoparticles
- PETPP
- Rhodium
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Lu, Y. D., Wang, Y. H., & Jin, Z. L. (2010). Rh nanoparticles stabilized by PEG-substituted triphenyl-phosphine: A highly active and recyclable catalyst for aqueous biphasic hydrogenation of benzene. Chinese Chemical Letters, 21(9), 1067-1070. https://doi.org/10.1016/j.cclet.2010.04.013