Rapid thermolysis studies of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O and Cd(CHZ)2(TNR)(H2O)

Xiao Li Zuo; Xiao Jing Qiao; Yuan Hua Sun; Tong Lai Zhang; Jian Guo Zhang; Li Yang; Shao Zong Wang

doi:10.1002/cjoc.200790175

Rapid thermolysis studies of [Pb₂(TNR)₂(CHZ) ₂(H₂O)₂]·4H₂O and Cd(CHZ)₂(TNR)(H₂O)

Xiao Li Zuo^*, Xiao Jing Qiao, Yuan Hua Sun, Tong Lai Zhang, Jian Guo Zhang, Li Yang, Shao Zong Wang

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb₂(TNR)₂(CHZ)₂(H ₂O)₂]·4H₂O and Cd(CHZ) ₂(TNR)(H₂O) under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb₂(TNR)₂(CHZ) ₂(H₂O)₂]·4H₂O are NH ₃, H₂O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd(CHZ)₂(TNR)(H₂O). Thus Cd(CHZ)₂(TNR)(H₂O) is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb₂(TNR) ₂(CHZ)₂(H₂O)₂]·4H ₂O is higher than that of Cd(CHZ)₂(TNR)(H₂O), there is no HNCO in the combustion products and the amount of NO is less than the experiment result from T-jump/FTIR.

Original language	English
Pages (from-to)	906-909
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	25
Issue number	7
DOIs	https://doi.org/10.1002/cjoc.200790175
Publication status	Published - Jul 2007

Keywords

Chromium complex
Lead complex
Real code
T-jump/FTIR

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10.1002/cjoc.200790175

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@article{0a4b49352c204065888cac29fb52591e,

title = "Rapid thermolysis studies of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O and Cd(CHZ)2(TNR)(H2O)",

abstract = "T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb2(TNR)2(CHZ)2(H 2O)2]·4H2O and Cd(CHZ) 2(TNR)(H2O) under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O are NH 3, H2O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd(CHZ)2(TNR)(H2O). Thus Cd(CHZ)2(TNR)(H2O) is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb2(TNR) 2(CHZ)2(H2O)2]·4H 2O is higher than that of Cd(CHZ)2(TNR)(H2O), there is no HNCO in the combustion products and the amount of NO is less than the experiment result from T-jump/FTIR.",

keywords = "Chromium complex, Lead complex, Real code, T-jump/FTIR",

author = "Zuo, {Xiao Li} and Qiao, {Xiao Jing} and Sun, {Yuan Hua} and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Li Yang and Wang, {Shao Zong}",

year = "2007",

month = jul,

doi = "10.1002/cjoc.200790175",

language = "English",

volume = "25",

pages = "906--909",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley & Sons Inc.",

number = "7",

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T1 - Rapid thermolysis studies of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O and Cd(CHZ)2(TNR)(H2O)

AU - Zuo, Xiao Li

AU - Qiao, Xiao Jing

AU - Sun, Yuan Hua

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Yang, Li

AU - Wang, Shao Zong

PY - 2007/7

Y1 - 2007/7

N2 - T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb2(TNR)2(CHZ)2(H 2O)2]·4H2O and Cd(CHZ) 2(TNR)(H2O) under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O are NH 3, H2O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd(CHZ)2(TNR)(H2O). Thus Cd(CHZ)2(TNR)(H2O) is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb2(TNR) 2(CHZ)2(H2O)2]·4H 2O is higher than that of Cd(CHZ)2(TNR)(H2O), there is no HNCO in the combustion products and the amount of NO is less than the experiment result from T-jump/FTIR.

AB - T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb2(TNR)2(CHZ)2(H 2O)2]·4H2O and Cd(CHZ) 2(TNR)(H2O) under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb2(TNR)2(CHZ) 2(H2O)2]·4H2O are NH 3, H2O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd(CHZ)2(TNR)(H2O). Thus Cd(CHZ)2(TNR)(H2O) is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb2(TNR) 2(CHZ)2(H2O)2]·4H 2O is higher than that of Cd(CHZ)2(TNR)(H2O), there is no HNCO in the combustion products and the amount of NO is less than the experiment result from T-jump/FTIR.

KW - Chromium complex

KW - Lead complex

KW - Real code

KW - T-jump/FTIR

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DO - 10.1002/cjoc.200790175

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Rapid thermolysis studies of [Pb₂(TNR)₂(CHZ) ₂(H₂O)₂]·4H₂O and Cd(CHZ)₂(TNR)(H₂O)

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