Purity Analysis Method of Dihydroxylammonium 5,5ʹ-Bistetrazole-1,1ʹ-diolate (TKX-50)

Shu Ling Xiong; Shu Sen Chen; Li Jie Li; Shao Hua Jin; Jing Lin Li

doi:10.1080/07370652.2015.1061618

Purity Analysis Method of Dihydroxylammonium 5,5ʹ-Bistetrazole-1,1ʹ-diolate (TKX-50)

Shu Ling Xiong, Shu Sen Chen, Li Jie Li^*, Shao Hua Jin, Jing Lin Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A method for purity analysis of dihydroxylammonium 5,5ʹ-bistetrazole-1,1ʹ-diolate (TKX-50) using high-performance liquid chromatography (HPLC) was established by optimizing the chromatographic conditions: the detection wavelength was set at 200 nm, and the sample was separated by reverse-phase column (SinoChrom ODS-BP, 4.6 mm × 200 mm, 5 μm) using binary mobile phase acetonitrile and water (volume ratio of 50/50) with a flow rate of 1.0 mL/min at column temperature of 25°C. Normalization method, external standard method, and internal standard method were used to analyze the purity of TKX-50. The results indicate that the precision and accuracy of each method can satisfy the requirements of product analysis; however, the external standard method possesses higher accuracy and precision by comparison and is suggested to analyze the purity of TKX-50.

Original language	English
Pages (from-to)	279-287
Number of pages	9
Journal	Journal of Energetic Materials
Volume	34
Issue number	3
DOIs	https://doi.org/10.1080/07370652.2015.1061618
Publication status	Published - 2 Jul 2016

Keywords

HPLC
TKX-50
external standard method
purity analysis

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10.1080/07370652.2015.1061618

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title = "Purity Analysis Method of Dihydroxylammonium 5,5ʹ-Bistetrazole-1,1ʹ-diolate (TKX-50)",

abstract = "A method for purity analysis of dihydroxylammonium 5,5ʹ-bistetrazole-1,1ʹ-diolate (TKX-50) using high-performance liquid chromatography (HPLC) was established by optimizing the chromatographic conditions: the detection wavelength was set at 200 nm, and the sample was separated by reverse-phase column (SinoChrom ODS-BP, 4.6 mm × 200 mm, 5 μm) using binary mobile phase acetonitrile and water (volume ratio of 50/50) with a flow rate of 1.0 mL/min at column temperature of 25°C. Normalization method, external standard method, and internal standard method were used to analyze the purity of TKX-50. The results indicate that the precision and accuracy of each method can satisfy the requirements of product analysis; however, the external standard method possesses higher accuracy and precision by comparison and is suggested to analyze the purity of TKX-50.",

keywords = "HPLC, TKX-50, external standard method, purity analysis",

author = "Xiong, {Shu Ling} and Chen, {Shu Sen} and Li, {Li Jie} and Jin, {Shao Hua} and Li, {Jing Lin}",

note = "Publisher Copyright: Copyright {\textcopyright} Taylor & Francis Group, LLC.",

year = "2016",

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day = "2",

doi = "10.1080/07370652.2015.1061618",

language = "English",

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T1 - Purity Analysis Method of Dihydroxylammonium 5,5ʹ-Bistetrazole-1,1ʹ-diolate (TKX-50)

AU - Xiong, Shu Ling

AU - Chen, Shu Sen

AU - Li, Li Jie

AU - Jin, Shao Hua

AU - Li, Jing Lin

PY - 2016/7/2

Y1 - 2016/7/2

N2 - A method for purity analysis of dihydroxylammonium 5,5ʹ-bistetrazole-1,1ʹ-diolate (TKX-50) using high-performance liquid chromatography (HPLC) was established by optimizing the chromatographic conditions: the detection wavelength was set at 200 nm, and the sample was separated by reverse-phase column (SinoChrom ODS-BP, 4.6 mm × 200 mm, 5 μm) using binary mobile phase acetonitrile and water (volume ratio of 50/50) with a flow rate of 1.0 mL/min at column temperature of 25°C. Normalization method, external standard method, and internal standard method were used to analyze the purity of TKX-50. The results indicate that the precision and accuracy of each method can satisfy the requirements of product analysis; however, the external standard method possesses higher accuracy and precision by comparison and is suggested to analyze the purity of TKX-50.

AB - A method for purity analysis of dihydroxylammonium 5,5ʹ-bistetrazole-1,1ʹ-diolate (TKX-50) using high-performance liquid chromatography (HPLC) was established by optimizing the chromatographic conditions: the detection wavelength was set at 200 nm, and the sample was separated by reverse-phase column (SinoChrom ODS-BP, 4.6 mm × 200 mm, 5 μm) using binary mobile phase acetonitrile and water (volume ratio of 50/50) with a flow rate of 1.0 mL/min at column temperature of 25°C. Normalization method, external standard method, and internal standard method were used to analyze the purity of TKX-50. The results indicate that the precision and accuracy of each method can satisfy the requirements of product analysis; however, the external standard method possesses higher accuracy and precision by comparison and is suggested to analyze the purity of TKX-50.

KW - HPLC

KW - TKX-50

KW - external standard method

KW - purity analysis

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DO - 10.1080/07370652.2015.1061618

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SN - 0737-0652

VL - 34

SP - 279

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JO - Journal of Energetic Materials

JF - Journal of Energetic Materials

IS - 3

ER -

Purity Analysis Method of Dihydroxylammonium 5,5ʹ-Bistetrazole-1,1ʹ-diolate (TKX-50)

Abstract

Keywords

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