Preparation of H3PW12O40/MCM-48 and its photocatalytic degradation of pesticides

Xia Liu*, Yan Zhou Li, Qiang Gan, Chang Gen Feng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A composite catalyst H3PW12O40/MCM-48 was prepared by loading photocatalyst phosphotungstic acid H3PW12O40 (HPW) to molecular sieve MCM-48 by impregnation method, and its structure was characterized by Fourier transform infrared (FT-IR) spectra, small angle X-ray diffraction (XRD) patterns, nitrogen adsorption analysis and High-resolution transmission electron microscopy (HRTEM) analysis. Photocatalytic degradation activities of HPW/MCM-48 against pesticides imidacloprid and paraquat were evaluated under UV radiation (365 nm). The results show that HPW/MCM-48 maintains the mesoprous molecular sieve structure of MCM-48 and the Keggin structure of HPW, while the BET surface area is 793.35 m2·g-1, pore volume is 1.46 cm3·g-1, average pore diameter is 2.76 nm, suggesting loading HPW on MCM-48 is a considerable way to improve its surface area. After 14 h UV irradiation (365 nm), 57.38% imidacloprid and 63.79% paraquat were degraded by 20 mg HPW/MCM-48 catalyst, while HPW and blank group degraded the two pesticides at the degradation rate of about 25% and 5%, respectively. Implying loading on MCM-48 could greaterly improve the degradation activity of HPW. The reslut of degradation kinetics show that, the degradation process of HPW/MCM-48 fits first order kinetics equation. The rate constant Ka of HPW/MCM-48 toward imidacloprid and paraquat are 0.089 h and 0.117 h, with the half-life t1/2 of 7.8 h and 5.9 h, respectively.

Original languageEnglish
Pages (from-to)2157-2161
Number of pages5
JournalGuang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume34
Issue number8
DOIs
Publication statusPublished - Aug 2014

Keywords

  • Imidacloprid
  • MCM-48
  • Paraquat
  • Phosphotungstic acid
  • Photocatalytic degradation

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