Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

Heng Dao Quan, Hui e. Yang, Zhong Li, Jian Zhang Ren, Hui Li Li

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9 Citations (Scopus)

Abstract

1,1,1,2-Tetrafluoroethane was prepared in 97% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF3 and CoF2) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.

Original languageEnglish
Pages (from-to)193-199
Number of pages7
JournalJournal of Fluorine Chemistry
Volume111
Issue number2
DOIs
Publication statusPublished - 2001
Externally publishedYes

Keywords

  • 1,1,1,2-Tetrafluoroethane
  • 1,1,1-Trifluoro-2-chloroethane
  • Metal fluoride
  • Porous aluminum fluoride

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