Preparation, crystal structure, and thermal decomposition of a novel nitrogen-rich compound Zn3(ATZ)6(N3) 6 (ATZ = 4-amino-1,2,4-triazole, N% = 61.7%)

Wen Chao Tong; Li Yang; Bi Dong Wu; Tong Lai Zhang

doi:10.1002/zaac.201300502

Preparation, crystal structure, and thermal decomposition of a novel nitrogen-rich compound Zn₃(ATZ)₆(N₃) ₆ (ATZ = 4-amino-1,2,4-triazole, N% = 61.7%)

Wen Chao Tong, Li Yang, Bi Dong Wu, Tong Lai Zhang

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The green nitrogen-rich coordination compound Zn₃(ATZ) ₆(N₃)₆ (1) (ATZ = 4-amino-1,2,4-triazole) was prepared and characterized by elemental analysis, IR spectroscopy, DSC and TG/DTG analyses. Its crystal structure was determined through X-ray single crystal diffraction at 153(2) K. The crystal belongs to the monoclinic P2 ₁/n space group with crystal parameters of the unit cell dimensions: a = 0.9187(3) nm, b = 1.4109(4) nm, c = 1.3395(4) nm, β = 92.593(4)°, V = 1.7345(8) nm³, Z = 4, D_c = 1.824 g·cm ^-3. The kinetic parameters of the first exothermic process of 1 were studied by the Kissinger's method and Ozawa-Doyle's method. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

Original language	English
Pages (from-to)	980-985
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	640
Issue number	5
DOIs	https://doi.org/10.1002/zaac.201300502
Publication status	Published - Apr 2014

Keywords

4-Amino-1,2,4-triazole
Azides
Crystal structure
Decomposition
Zinc

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title = "Preparation, crystal structure, and thermal decomposition of a novel nitrogen-rich compound Zn3(ATZ)6(N3) 6 (ATZ = 4-amino-1,2,4-triazole, N% = 61.7%)",

abstract = "The green nitrogen-rich coordination compound Zn3(ATZ) 6(N3)6 (1) (ATZ = 4-amino-1,2,4-triazole) was prepared and characterized by elemental analysis, IR spectroscopy, DSC and TG/DTG analyses. Its crystal structure was determined through X-ray single crystal diffraction at 153(2) K. The crystal belongs to the monoclinic P2 1/n space group with crystal parameters of the unit cell dimensions: a = 0.9187(3) nm, b = 1.4109(4) nm, c = 1.3395(4) nm, β = 92.593(4)°, V = 1.7345(8) nm3, Z = 4, Dc = 1.824 g·cm -3. The kinetic parameters of the first exothermic process of 1 were studied by the Kissinger's method and Ozawa-Doyle's method. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.",

keywords = "4-Amino-1,2,4-triazole, Azides, Crystal structure, Decomposition, Zinc",

author = "Tong, {Wen Chao} and Li Yang and Wu, {Bi Dong} and Zhang, {Tong Lai}",

year = "2014",

month = apr,

doi = "10.1002/zaac.201300502",

language = "English",

volume = "640",

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T1 - Preparation, crystal structure, and thermal decomposition of a novel nitrogen-rich compound Zn3(ATZ)6(N3) 6 (ATZ = 4-amino-1,2,4-triazole, N% = 61.7%)

AU - Tong, Wen Chao

AU - Yang, Li

AU - Wu, Bi Dong

AU - Zhang, Tong Lai

PY - 2014/4

Y1 - 2014/4

N2 - The green nitrogen-rich coordination compound Zn3(ATZ) 6(N3)6 (1) (ATZ = 4-amino-1,2,4-triazole) was prepared and characterized by elemental analysis, IR spectroscopy, DSC and TG/DTG analyses. Its crystal structure was determined through X-ray single crystal diffraction at 153(2) K. The crystal belongs to the monoclinic P2 1/n space group with crystal parameters of the unit cell dimensions: a = 0.9187(3) nm, b = 1.4109(4) nm, c = 1.3395(4) nm, β = 92.593(4)°, V = 1.7345(8) nm3, Z = 4, Dc = 1.824 g·cm -3. The kinetic parameters of the first exothermic process of 1 were studied by the Kissinger's method and Ozawa-Doyle's method. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

AB - The green nitrogen-rich coordination compound Zn3(ATZ) 6(N3)6 (1) (ATZ = 4-amino-1,2,4-triazole) was prepared and characterized by elemental analysis, IR spectroscopy, DSC and TG/DTG analyses. Its crystal structure was determined through X-ray single crystal diffraction at 153(2) K. The crystal belongs to the monoclinic P2 1/n space group with crystal parameters of the unit cell dimensions: a = 0.9187(3) nm, b = 1.4109(4) nm, c = 1.3395(4) nm, β = 92.593(4)°, V = 1.7345(8) nm3, Z = 4, Dc = 1.824 g·cm -3. The kinetic parameters of the first exothermic process of 1 were studied by the Kissinger's method and Ozawa-Doyle's method. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

KW - 4-Amino-1,2,4-triazole

KW - Azides

KW - Crystal structure

KW - Decomposition

KW - Zinc

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DO - 10.1002/zaac.201300502

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JO - Zeitschrift fur Anorganische und Allgemeine Chemie

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Preparation, crystal structure, and thermal decomposition of a novel nitrogen-rich compound Zn₃(ATZ)₆(N₃) ₆ (ATZ = 4-amino-1,2,4-triazole, N% = 61.7%)

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