Preparation and properties of sulfonated poly (2, 6-dimethyl-1, 4- phenylene oxide) / ionic liquid /phosphoric acid high temperature proton exchange composite membrane

Shanshan Wang, Qifeng Li, Fanghui Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A SPPO/IL composite membrane was obtained by self-assembly using the SPPO with the highest degree of sulfonation and the prepared ionic liquid (1-methyl-3-methylimidazolium). SPPO/IL composite membrane is doped with phosphoric acid to form SPPO/IL/PA composite membrane. The SPPO/IL composite membrane is immersed in PA for 24 h, the ion conductivity reaches 36.1 mS/cm. The mechanical stability (350°C), swelling (area 2.26%, volume 2.58%), and oxidation stability (4.2 h) are all acceptable. SPPO/IL/PA composite membranes have application potential as HTPEM materials. A sulfonated poly(2,6-dimethyl-1,4-phenylene oxide)/ionic liquid (SPPO/IL) composite membrane was obtained by self-assembly using the SPPO with the highest degree of sulfonation and the prepared ionic liquid (1-methyl-3-methylimidazolium). SPPO/IL composite membrane is doped with phosphoric acid to form SPPO/IL/PA composite membrane.

Original languageEnglish
Pages (from-to)650-658
Number of pages9
JournalPolymer-Plastics Technology and Materials
Volume60
Issue number6
DOIs
Publication statusPublished - 2021

Keywords

  • 4-phenylene oxide)(SPPO)
  • 6-dimethyl-1
  • Sulfonated poly (2
  • composite membrane
  • high-temperature proton exchange membrane
  • ionic liquid(IL)

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