Preparation and characterization of novel polyether/poly(vinylidene fluoride-hexa fluoroproyiene)-based solid polymer electrolytes

Ting Feng; Feng Wu; Chuan Wu; Ying Bai; Lin Ye; Zeng Guo Feng

Preparation and characterization of novel polyether/poly(vinylidene fluoride-hexa fluoroproyiene)-based solid polymer electrolytes

Ting Feng^*, Feng Wu, Chuan Wu, Ying Bai, Lin Ye, Zeng Guo Feng

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A series of Composite polymer electrolytes were prepared by blending a novel hyperbranched polyether (PHEMO) with different amount of poly(vinylidene fluoride-hexa fluoroproylene) (PVDF-HFP), The thermal stabilities and ionic conductivities of the as-prepared electrolytes were investigated by means of differential scanning calorimetric (DSC), thermogravimetric analysis (TGA) and alternating current impendence. The test results displayed that both the adding amount of PVDF-HFP and testing temperature had effect on ionic conductivities of the polymer electrolytes. When the mass ratio of PHEMO to PVDF-HFP was 2:1, the composites possessed excellent electrochemical and thermal stability, and the ion conductivity was 3.04 × 10^-5 S/cm at room temperature. TGA results showed that the composites had better thermal stability and they were benefit for the safety of lithium ion batteries.

Original language	English
Pages (from-to)	40-43
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	27
Issue number	SUPPL. 2
Publication status	Published - Dec 2007

Keywords

Hyperbranched polyether
Ionic conductivity
Lithium-ion battery
PVDF-HFP
Polymer electrolyte

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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@article{72bd2b63b6944e3990f35cfbb567d605,

title = "Preparation and characterization of novel polyether/poly(vinylidene fluoride-hexa fluoroproyiene)-based solid polymer electrolytes",

abstract = "A series of Composite polymer electrolytes were prepared by blending a novel hyperbranched polyether (PHEMO) with different amount of poly(vinylidene fluoride-hexa fluoroproylene) (PVDF-HFP), The thermal stabilities and ionic conductivities of the as-prepared electrolytes were investigated by means of differential scanning calorimetric (DSC), thermogravimetric analysis (TGA) and alternating current impendence. The test results displayed that both the adding amount of PVDF-HFP and testing temperature had effect on ionic conductivities of the polymer electrolytes. When the mass ratio of PHEMO to PVDF-HFP was 2:1, the composites possessed excellent electrochemical and thermal stability, and the ion conductivity was 3.04 × 10-5 S/cm at room temperature. TGA results showed that the composites had better thermal stability and they were benefit for the safety of lithium ion batteries.",

keywords = "Hyperbranched polyether, Ionic conductivity, Lithium-ion battery, PVDF-HFP, Polymer electrolyte",

author = "Ting Feng and Feng Wu and Chuan Wu and Ying Bai and Lin Ye and Feng, {Zeng Guo}",

year = "2007",

month = dec,

language = "English",

volume = "27",

pages = "40--43",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "SUPPL. 2",

}

TY - JOUR

T1 - Preparation and characterization of novel polyether/poly(vinylidene fluoride-hexa fluoroproyiene)-based solid polymer electrolytes

AU - Feng, Ting

AU - Wu, Feng

AU - Wu, Chuan

AU - Bai, Ying

AU - Ye, Lin

AU - Feng, Zeng Guo

PY - 2007/12

Y1 - 2007/12

N2 - A series of Composite polymer electrolytes were prepared by blending a novel hyperbranched polyether (PHEMO) with different amount of poly(vinylidene fluoride-hexa fluoroproylene) (PVDF-HFP), The thermal stabilities and ionic conductivities of the as-prepared electrolytes were investigated by means of differential scanning calorimetric (DSC), thermogravimetric analysis (TGA) and alternating current impendence. The test results displayed that both the adding amount of PVDF-HFP and testing temperature had effect on ionic conductivities of the polymer electrolytes. When the mass ratio of PHEMO to PVDF-HFP was 2:1, the composites possessed excellent electrochemical and thermal stability, and the ion conductivity was 3.04 × 10-5 S/cm at room temperature. TGA results showed that the composites had better thermal stability and they were benefit for the safety of lithium ion batteries.

AB - A series of Composite polymer electrolytes were prepared by blending a novel hyperbranched polyether (PHEMO) with different amount of poly(vinylidene fluoride-hexa fluoroproylene) (PVDF-HFP), The thermal stabilities and ionic conductivities of the as-prepared electrolytes were investigated by means of differential scanning calorimetric (DSC), thermogravimetric analysis (TGA) and alternating current impendence. The test results displayed that both the adding amount of PVDF-HFP and testing temperature had effect on ionic conductivities of the polymer electrolytes. When the mass ratio of PHEMO to PVDF-HFP was 2:1, the composites possessed excellent electrochemical and thermal stability, and the ion conductivity was 3.04 × 10-5 S/cm at room temperature. TGA results showed that the composites had better thermal stability and they were benefit for the safety of lithium ion batteries.

KW - Hyperbranched polyether

KW - Ionic conductivity

KW - Lithium-ion battery

KW - PVDF-HFP

KW - Polymer electrolyte

UR - http://www.scopus.com/inward/record.url?scp=40749123370&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:40749123370

SN - 1001-0645

VL - 27

SP - 40

EP - 43

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - SUPPL. 2

ER -

Preparation and characterization of novel polyether/poly(vinylidene fluoride-hexa fluoroproyiene)-based solid polymer electrolytes

Abstract

Keywords

UN SDGs

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