Preparation and Characterization of Hexahydro-1,3,5-trinitro-1,3,5-triazine/Ammonium Perchlorate Intermolecular Explosives

Guo Ping Li; Ya Zhong Liu; Meng Hui Liu; Chun Peng Chai; Yun Jun Luo

doi:10.1002/prep.201500229

Preparation and Characterization of Hexahydro-1,3,5-trinitro-1,3,5-triazine/Ammonium Perchlorate Intermolecular Explosives

Guo Ping Li, Ya Zhong Liu, Meng Hui Liu, Chun Peng Chai, Yun Jun Luo^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Hexahydro-1,3,5-trinitro-1,3,5-triazine/ammonium perchlorate/glycidyl azide polymer (RDX/AP/GAP) intermolecular explosives (IMX) with different proportions of RDX to AP were prepared by sol-gel method, and the structure and performance was characterized by Brunauer-Emmett-Teller measurements (BET), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the specific surface area of RDX/AP/GAP IMX decreased with the addition of AP. The crystals of AP and RDX in RDX/AP/GAP intermolecular explosives were in the range of 20–48 nm and 23–55 nm, respectively. In addition, RDX/AP/GAP intermolecular explosives had the largest heat release at zero balance.

Original language	English
Pages (from-to)	641-644
Number of pages	4
Journal	Propellants, Explosives, Pyrotechnics
Volume	41
Issue number	4
DOIs	https://doi.org/10.1002/prep.201500229
Publication status	Published - 1 Aug 2016

Keywords

Intermolecular explosive
Oxygen balance
Sol-gel method

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10.1002/prep.201500229

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@article{edeec14c938e4932936f43b6c7529813,

title = "Preparation and Characterization of Hexahydro-1,3,5-trinitro-1,3,5-triazine/Ammonium Perchlorate Intermolecular Explosives",

abstract = "Hexahydro-1,3,5-trinitro-1,3,5-triazine/ammonium perchlorate/glycidyl azide polymer (RDX/AP/GAP) intermolecular explosives (IMX) with different proportions of RDX to AP were prepared by sol-gel method, and the structure and performance was characterized by Brunauer-Emmett-Teller measurements (BET), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the specific surface area of RDX/AP/GAP IMX decreased with the addition of AP. The crystals of AP and RDX in RDX/AP/GAP intermolecular explosives were in the range of 20–48 nm and 23–55 nm, respectively. In addition, RDX/AP/GAP intermolecular explosives had the largest heat release at zero balance.",

keywords = "Intermolecular explosive, Oxygen balance, Sol-gel method",

author = "Li, {Guo Ping} and Liu, {Ya Zhong} and Liu, {Meng Hui} and Chai, {Chun Peng} and Luo, {Yun Jun}",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = aug,

day = "1",

doi = "10.1002/prep.201500229",

language = "English",

volume = "41",

pages = "641--644",

journal = "Propellants, Explosives, Pyrotechnics",

issn = "0721-3115",

publisher = "Wiley-VCH Verlag",

number = "4",

}

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T1 - Preparation and Characterization of Hexahydro-1,3,5-trinitro-1,3,5-triazine/Ammonium Perchlorate Intermolecular Explosives

AU - Li, Guo Ping

AU - Liu, Ya Zhong

AU - Liu, Meng Hui

AU - Chai, Chun Peng

AU - Luo, Yun Jun

PY - 2016/8/1

Y1 - 2016/8/1

N2 - Hexahydro-1,3,5-trinitro-1,3,5-triazine/ammonium perchlorate/glycidyl azide polymer (RDX/AP/GAP) intermolecular explosives (IMX) with different proportions of RDX to AP were prepared by sol-gel method, and the structure and performance was characterized by Brunauer-Emmett-Teller measurements (BET), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the specific surface area of RDX/AP/GAP IMX decreased with the addition of AP. The crystals of AP and RDX in RDX/AP/GAP intermolecular explosives were in the range of 20–48 nm and 23–55 nm, respectively. In addition, RDX/AP/GAP intermolecular explosives had the largest heat release at zero balance.

AB - Hexahydro-1,3,5-trinitro-1,3,5-triazine/ammonium perchlorate/glycidyl azide polymer (RDX/AP/GAP) intermolecular explosives (IMX) with different proportions of RDX to AP were prepared by sol-gel method, and the structure and performance was characterized by Brunauer-Emmett-Teller measurements (BET), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the specific surface area of RDX/AP/GAP IMX decreased with the addition of AP. The crystals of AP and RDX in RDX/AP/GAP intermolecular explosives were in the range of 20–48 nm and 23–55 nm, respectively. In addition, RDX/AP/GAP intermolecular explosives had the largest heat release at zero balance.

KW - Intermolecular explosive

KW - Oxygen balance

KW - Sol-gel method

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DO - 10.1002/prep.201500229

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SN - 0721-3115

VL - 41

SP - 641

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JO - Propellants, Explosives, Pyrotechnics

JF - Propellants, Explosives, Pyrotechnics

IS - 4

ER -

Preparation and Characterization of Hexahydro-1,3,5-trinitro-1,3,5-triazine/Ammonium Perchlorate Intermolecular Explosives

Abstract

Keywords

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