Preparation and characterization of hexaalkylguanidinium NTO energetic salts

Zhi Yong Gan; Chun Peng Chai; Yun Jun Luo

Preparation and characterization of hexaalkylguanidinium NTO energetic salts

Zhi Yong Gan, Chun Peng Chai^*, Yun Jun Luo

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Four kinds of hexaalkylguanidinium 3-Nitro-1, 2, 4-triazole5-one (C _n-NTO, n=2, 3, 4, 5) energetic ionic compounds were synthesized. Their structures were identified by IR, ¹HNMR, and their density, solubility, thermal properties were studied. The results show that NTO hexaalkylguanidinium ionic salts could dissolve in most of organic solvents. The maximum decomposition temperature is about 250°C. In the second heating process of DSC, the NTO ionic salts experienced four kinds of phases, i.e. glassy, supercooled state, crystalline solid and liquid.

Original language	English
Pages (from-to)	750-753
Number of pages	4
Journal	Guti Huojian Jishu/Journal of Solid Rocket Technology
Volume	34
Issue number	6
Publication status	Published - Dec 2011

Keywords

Energetic materials
Hexaalkylguanidinium NTO salts
Synthesis
Thermal properties

Cite this

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title = "Preparation and characterization of hexaalkylguanidinium NTO energetic salts",

abstract = "Four kinds of hexaalkylguanidinium 3-Nitro-1, 2, 4-triazole5-one (C n-NTO, n=2, 3, 4, 5) energetic ionic compounds were synthesized. Their structures were identified by IR, 1HNMR, and their density, solubility, thermal properties were studied. The results show that NTO hexaalkylguanidinium ionic salts could dissolve in most of organic solvents. The maximum decomposition temperature is about 250°C. In the second heating process of DSC, the NTO ionic salts experienced four kinds of phases, i.e. glassy, supercooled state, crystalline solid and liquid.",

keywords = "Energetic materials, Hexaalkylguanidinium NTO salts, Synthesis, Thermal properties",

author = "Gan, {Zhi Yong} and Chai, {Chun Peng} and Luo, {Yun Jun}",

year = "2011",

month = dec,

language = "English",

volume = "34",

pages = "750--753",

journal = "Guti Huojian Jishu/Journal of Solid Rocket Technology",

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T1 - Preparation and characterization of hexaalkylguanidinium NTO energetic salts

AU - Gan, Zhi Yong

AU - Chai, Chun Peng

AU - Luo, Yun Jun

PY - 2011/12

Y1 - 2011/12

N2 - Four kinds of hexaalkylguanidinium 3-Nitro-1, 2, 4-triazole5-one (C n-NTO, n=2, 3, 4, 5) energetic ionic compounds were synthesized. Their structures were identified by IR, 1HNMR, and their density, solubility, thermal properties were studied. The results show that NTO hexaalkylguanidinium ionic salts could dissolve in most of organic solvents. The maximum decomposition temperature is about 250°C. In the second heating process of DSC, the NTO ionic salts experienced four kinds of phases, i.e. glassy, supercooled state, crystalline solid and liquid.

AB - Four kinds of hexaalkylguanidinium 3-Nitro-1, 2, 4-triazole5-one (C n-NTO, n=2, 3, 4, 5) energetic ionic compounds were synthesized. Their structures were identified by IR, 1HNMR, and their density, solubility, thermal properties were studied. The results show that NTO hexaalkylguanidinium ionic salts could dissolve in most of organic solvents. The maximum decomposition temperature is about 250°C. In the second heating process of DSC, the NTO ionic salts experienced four kinds of phases, i.e. glassy, supercooled state, crystalline solid and liquid.

KW - Energetic materials

KW - Hexaalkylguanidinium NTO salts

KW - Synthesis

KW - Thermal properties

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M3 - Article

AN - SCOPUS:84856547428

SN - 1006-2793

VL - 34

SP - 750

EP - 753

JO - Guti Huojian Jishu/Journal of Solid Rocket Technology

JF - Guti Huojian Jishu/Journal of Solid Rocket Technology

IS - 6

ER -

Preparation and characterization of hexaalkylguanidinium NTO energetic salts

Abstract

Keywords

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