Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

Xiao Dong Yang; Rui Zhu; Li Sun; Rui Yun Guo; Jie Zhang

doi:10.1021/acs.inorgchem.7b03108

Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

Xiao Dong Yang, Rui Zhu, Li Sun, Rui Yun Guo, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

Original language	English
Pages (from-to)	2724-2729
Number of pages	6
Journal	Inorganic Chemistry
Volume	57
Issue number	5
DOIs	https://doi.org/10.1021/acs.inorgchem.7b03108
Publication status	Published - 5 Mar 2018

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10.1021/acs.inorgchem.7b03108

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title = "Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer",

abstract = "Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine {"}heart{"} is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine {"}heart{"} promotes the occurrence of this mechanical movement.",

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AU - Yang, Xiao Dong

AU - Zhu, Rui

AU - Sun, Li

AU - Guo, Rui Yun

AU - Zhang, Jie

PY - 2018/3/5

Y1 - 2018/3/5

N2 - Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

AB - Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

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M3 - Article

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

Abstract

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