Oxidation-promoted interfacial synthesis of redox-active bis(diimino)nickel nanosheet

Eunice J.H. Phua; Kuo Hui Wu; Keisuke Wada; Tetsuro Kusamoto; Hiroaki Maeda; Jian Cao; Ryota Sakamoto; Hiroyasu Masunaga; Sono Sasaki; Jia Wei Mei; Wei Jiang; Feng Liu; Hiroshi Nishihara

doi:10.1246/cl.170928

Oxidation-promoted interfacial synthesis of redox-active bis(diimino)nickel nanosheet

Eunice J.H. Phua, Kuo Hui Wu, Keisuke Wada, Tetsuro Kusamoto, Hiroaki Maeda, Jian Cao, Ryota Sakamoto, Hiroyasu Masunaga, Sono Sasaki, Jia Wei Mei, Wei Jiang, Feng Liu, Hiroshi Nishihara^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Bis(diimino)nickel (NiDI) nanosheet is prepared by two methods of oxidation-promoted interfacial coordination reactions of nickel(II) ions with hexaaminobenzene. The thickness of the large chemically formed NiDI nanosheet can be controlled from atomic layers to thousands of layers. The morphology of electrochemically formed NiDI-modified electrode achievable within a minute suggests longitudinal growth of nanosheets at the surface. Increasing capacity of the NiDI with its amount indicates NiDI as a promising energy storage material.

Original language	English
Pages (from-to)	126-129
Number of pages	4
Journal	Chemistry Letters
Volume	47
Issue number	2
DOIs	https://doi.org/10.1246/cl.170928
Publication status	Published - 2018
Externally published	Yes

Keywords

Bis(diimino)nickel
Coordination nanosheet (CONASH)
Electropolymerization

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10.1246/cl.170928

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title = "Oxidation-promoted interfacial synthesis of redox-active bis(diimino)nickel nanosheet",

abstract = "Bis(diimino)nickel (NiDI) nanosheet is prepared by two methods of oxidation-promoted interfacial coordination reactions of nickel(II) ions with hexaaminobenzene. The thickness of the large chemically formed NiDI nanosheet can be controlled from atomic layers to thousands of layers. The morphology of electrochemically formed NiDI-modified electrode achievable within a minute suggests longitudinal growth of nanosheets at the surface. Increasing capacity of the NiDI with its amount indicates NiDI as a promising energy storage material.",

keywords = "Bis(diimino)nickel, Coordination nanosheet (CONASH), Electropolymerization",

author = "Phua, {Eunice J.H.} and Wu, {Kuo Hui} and Keisuke Wada and Tetsuro Kusamoto and Hiroaki Maeda and Jian Cao and Ryota Sakamoto and Hiroyasu Masunaga and Sono Sasaki and Mei, {Jia Wei} and Wei Jiang and Feng Liu and Hiroshi Nishihara",

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year = "2018",

doi = "10.1246/cl.170928",

language = "English",

volume = "47",

pages = "126--129",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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TY - JOUR

T1 - Oxidation-promoted interfacial synthesis of redox-active bis(diimino)nickel nanosheet

AU - Phua, Eunice J.H.

AU - Wu, Kuo Hui

AU - Wada, Keisuke

AU - Kusamoto, Tetsuro

AU - Maeda, Hiroaki

AU - Cao, Jian

AU - Sakamoto, Ryota

AU - Masunaga, Hiroyasu

AU - Sasaki, Sono

AU - Mei, Jia Wei

AU - Jiang, Wei

AU - Liu, Feng

AU - Nishihara, Hiroshi

PY - 2018

Y1 - 2018

N2 - Bis(diimino)nickel (NiDI) nanosheet is prepared by two methods of oxidation-promoted interfacial coordination reactions of nickel(II) ions with hexaaminobenzene. The thickness of the large chemically formed NiDI nanosheet can be controlled from atomic layers to thousands of layers. The morphology of electrochemically formed NiDI-modified electrode achievable within a minute suggests longitudinal growth of nanosheets at the surface. Increasing capacity of the NiDI with its amount indicates NiDI as a promising energy storage material.

AB - Bis(diimino)nickel (NiDI) nanosheet is prepared by two methods of oxidation-promoted interfacial coordination reactions of nickel(II) ions with hexaaminobenzene. The thickness of the large chemically formed NiDI nanosheet can be controlled from atomic layers to thousands of layers. The morphology of electrochemically formed NiDI-modified electrode achievable within a minute suggests longitudinal growth of nanosheets at the surface. Increasing capacity of the NiDI with its amount indicates NiDI as a promising energy storage material.

KW - Bis(diimino)nickel

KW - Coordination nanosheet (CONASH)

KW - Electropolymerization

UR - http://www.scopus.com/inward/record.url?scp=85039422247&partnerID=8YFLogxK

U2 - 10.1246/cl.170928

DO - 10.1246/cl.170928

M3 - Article

AN - SCOPUS:85039422247

SN - 0366-7022

VL - 47

SP - 126

EP - 129

JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

ER -

Oxidation-promoted interfacial synthesis of redox-active bis(diimino)nickel nanosheet

Abstract

Keywords

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