Novel hybrids constructed from Keggin-polyoxometalate and mixed copper complex

Chun Mei Wang; Shou Tian Zheng; Guo Yu Yang

doi:10.1007/s10876-009-0236-7

Novel hybrids constructed from Keggin-polyoxometalate and mixed copper complex

Chun Mei Wang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Two new Keggin-polyoxometalate hybrids, {[Cu₂(4,4′-bpy)₂][PW₁₀^VIW₂^VO₄₀]}[Cu₂(obpy)₂]₄ · 2 H₂O (1) and {[Cu₄(2,2′-bpy)₄(4,4′-bpy)₃][SiW₁₂O₄₀]} · 2H₂O (2) (4,4′-/2,2′-bpy = 4,4′-/2,2′-bipyridyl, Hobpy = 6-hydroxy-2,2′-bipyridyl), were hydrothermally synthesized and structurally characterized. Gillard type hydration of 2,2′-bipy is observed during the synthesis of 1, resulting in a new obpy ligand in situ. X-ray structural analyses show that 1 consists of 1D hybrid chain {[Cu₂(4,4′-bpy)₂][PW₁₀^VIW₂^VO₄₀]}_∞ and [Cu₂(obpy)₂] dimer, whereas 2 possesses 1D hybrid structure based on Keggin-type [SiW₁₂O₄₀]^4- anions and tetra-nuclear copper complexes [Cu₄(2,2′-bpy)₄(4,4′-bpy)₃]⁴⁺. Both compounds present interesting supramolecular architectures based on π-π stacking and hydrogen bonds.

Original language	English
Pages (from-to)	489-501
Number of pages	13
Journal	Journal of Cluster Science
Volume	20
Issue number	3
DOIs	https://doi.org/10.1007/s10876-009-0236-7
Publication status	Published - 2009
Externally published	Yes

Keywords

Hydrothermal synthesis
In situ
Organic-inorganic hybrid
Polyoxometalates
Structures

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@article{5d7da5ec9b6746ce9031de2533ee1f14,

title = "Novel hybrids constructed from Keggin-polyoxometalate and mixed copper complex",

abstract = "Two new Keggin-polyoxometalate hybrids, {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}[Cu2(obpy)2]4 · 2 H2O (1) and {[Cu4(2,2′-bpy)4(4,4′-bpy)3][SiW12O40]} · 2H2O (2) (4,4′-/2,2′-bpy = 4,4′-/2,2′-bipyridyl, Hobpy = 6-hydroxy-2,2′-bipyridyl), were hydrothermally synthesized and structurally characterized. Gillard type hydration of 2,2′-bipy is observed during the synthesis of 1, resulting in a new obpy ligand in situ. X-ray structural analyses show that 1 consists of 1D hybrid chain {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}∞ and [Cu2(obpy)2] dimer, whereas 2 possesses 1D hybrid structure based on Keggin-type [SiW12O40]4- anions and tetra-nuclear copper complexes [Cu4(2,2′-bpy)4(4,4′-bpy)3]4+. Both compounds present interesting supramolecular architectures based on π-π stacking and hydrogen bonds.",

keywords = "Hydrothermal synthesis, In situ, Organic-inorganic hybrid, Polyoxometalates, Structures",

author = "Wang, {Chun Mei} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2009",

doi = "10.1007/s10876-009-0236-7",

language = "English",

volume = "20",

pages = "489--501",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Novel hybrids constructed from Keggin-polyoxometalate and mixed copper complex

AU - Wang, Chun Mei

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - Two new Keggin-polyoxometalate hybrids, {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}[Cu2(obpy)2]4 · 2 H2O (1) and {[Cu4(2,2′-bpy)4(4,4′-bpy)3][SiW12O40]} · 2H2O (2) (4,4′-/2,2′-bpy = 4,4′-/2,2′-bipyridyl, Hobpy = 6-hydroxy-2,2′-bipyridyl), were hydrothermally synthesized and structurally characterized. Gillard type hydration of 2,2′-bipy is observed during the synthesis of 1, resulting in a new obpy ligand in situ. X-ray structural analyses show that 1 consists of 1D hybrid chain {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}∞ and [Cu2(obpy)2] dimer, whereas 2 possesses 1D hybrid structure based on Keggin-type [SiW12O40]4- anions and tetra-nuclear copper complexes [Cu4(2,2′-bpy)4(4,4′-bpy)3]4+. Both compounds present interesting supramolecular architectures based on π-π stacking and hydrogen bonds.

AB - Two new Keggin-polyoxometalate hybrids, {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}[Cu2(obpy)2]4 · 2 H2O (1) and {[Cu4(2,2′-bpy)4(4,4′-bpy)3][SiW12O40]} · 2H2O (2) (4,4′-/2,2′-bpy = 4,4′-/2,2′-bipyridyl, Hobpy = 6-hydroxy-2,2′-bipyridyl), were hydrothermally synthesized and structurally characterized. Gillard type hydration of 2,2′-bipy is observed during the synthesis of 1, resulting in a new obpy ligand in situ. X-ray structural analyses show that 1 consists of 1D hybrid chain {[Cu2(4,4′-bpy)2][PW10VIW2VO40]}∞ and [Cu2(obpy)2] dimer, whereas 2 possesses 1D hybrid structure based on Keggin-type [SiW12O40]4- anions and tetra-nuclear copper complexes [Cu4(2,2′-bpy)4(4,4′-bpy)3]4+. Both compounds present interesting supramolecular architectures based on π-π stacking and hydrogen bonds.

KW - Hydrothermal synthesis

KW - In situ

KW - Organic-inorganic hybrid

KW - Polyoxometalates

KW - Structures

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U2 - 10.1007/s10876-009-0236-7

DO - 10.1007/s10876-009-0236-7

M3 - Article

AN - SCOPUS:70350023442

SN - 1040-7278

VL - 20

SP - 489

EP - 501

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

Novel hybrids constructed from Keggin-polyoxometalate and mixed copper complex

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