(NH4)6[Mn3B6P9O 36(OH)3]·4H2O: A new open-framework manganese borophosphate synthesized by using boric acid flux method

Weiting Yang; Jiyang Li; Tianyi Na; Jin Xu; Lei Wang; Jihong Yu; Ruren Xu

doi:10.1039/c0dt01475c

(NH₄)₆[Mn₃B₆P₉O ₃₆(OH)₃]·4H₂O: A new open-framework manganese borophosphate synthesized by using boric acid flux method

Weiting Yang, Jiyang Li, Tianyi Na, Jin Xu, Lei Wang, Jihong Yu^*, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A new three-dimensional (3-D) open-framework manganese borophosphate, (NH₄)₆[Mn₃B₆P₉O ₃₆(OH)₃]·4H₂O (denoted as MnBPO-CJ31), has been synthesized by using boric acid flux method. Its anionic framework structure is constructed by the connection of MnO₆ octahedra and BO₄, PO₄ and PO₃(OH) tetrahedra. It contains 12-ring channels along the [001] direction with a pore diameter of 7.1 Å. It is the first borophosphate featuring a 3-D anionic partial structure with a B/P ratio of 2/3 and an unprecedented fifteen mer tetrahedral fundamental building unit (FBU) [B₆P₉O₃₆(OH)₃] exists in this compound. NH₄⁺ ions locate in the void space to balance the negative charge of the inorganic framework. The compound is further characterized by powder XRD, ICP, CHN, TGA and IR analyses. Magnetic study reveals that MnBPO-CJ31 shows interesting canted antiferromagnetic behaviour at low temperature.

Original language	English
Pages (from-to)	2549-2554
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	11
DOIs	https://doi.org/10.1039/c0dt01475c
Publication status	Published - 21 Mar 2011
Externally published	Yes

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title = "(NH4)6[Mn3B6P9O 36(OH)3]·4H2O: A new open-framework manganese borophosphate synthesized by using boric acid flux method",

abstract = "A new three-dimensional (3-D) open-framework manganese borophosphate, (NH4)6[Mn3B6P9O 36(OH)3]·4H2O (denoted as MnBPO-CJ31), has been synthesized by using boric acid flux method. Its anionic framework structure is constructed by the connection of MnO6 octahedra and BO4, PO4 and PO3(OH) tetrahedra. It contains 12-ring channels along the [001] direction with a pore diameter of 7.1 {\AA}. It is the first borophosphate featuring a 3-D anionic partial structure with a B/P ratio of 2/3 and an unprecedented fifteen mer tetrahedral fundamental building unit (FBU) [B6P9O36(OH)3] exists in this compound. NH4+ ions locate in the void space to balance the negative charge of the inorganic framework. The compound is further characterized by powder XRD, ICP, CHN, TGA and IR analyses. Magnetic study reveals that MnBPO-CJ31 shows interesting canted antiferromagnetic behaviour at low temperature.",

author = "Weiting Yang and Jiyang Li and Tianyi Na and Jin Xu and Lei Wang and Jihong Yu and Ruren Xu",

year = "2011",

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doi = "10.1039/c0dt01475c",

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journal = "Dalton Transactions",

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T1 - (NH4)6[Mn3B6P9O 36(OH)3]·4H2O

T2 - A new open-framework manganese borophosphate synthesized by using boric acid flux method

AU - Yang, Weiting

AU - Li, Jiyang

AU - Na, Tianyi

AU - Xu, Jin

AU - Wang, Lei

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2011/3/21

Y1 - 2011/3/21

N2 - A new three-dimensional (3-D) open-framework manganese borophosphate, (NH4)6[Mn3B6P9O 36(OH)3]·4H2O (denoted as MnBPO-CJ31), has been synthesized by using boric acid flux method. Its anionic framework structure is constructed by the connection of MnO6 octahedra and BO4, PO4 and PO3(OH) tetrahedra. It contains 12-ring channels along the [001] direction with a pore diameter of 7.1 Å. It is the first borophosphate featuring a 3-D anionic partial structure with a B/P ratio of 2/3 and an unprecedented fifteen mer tetrahedral fundamental building unit (FBU) [B6P9O36(OH)3] exists in this compound. NH4+ ions locate in the void space to balance the negative charge of the inorganic framework. The compound is further characterized by powder XRD, ICP, CHN, TGA and IR analyses. Magnetic study reveals that MnBPO-CJ31 shows interesting canted antiferromagnetic behaviour at low temperature.

AB - A new three-dimensional (3-D) open-framework manganese borophosphate, (NH4)6[Mn3B6P9O 36(OH)3]·4H2O (denoted as MnBPO-CJ31), has been synthesized by using boric acid flux method. Its anionic framework structure is constructed by the connection of MnO6 octahedra and BO4, PO4 and PO3(OH) tetrahedra. It contains 12-ring channels along the [001] direction with a pore diameter of 7.1 Å. It is the first borophosphate featuring a 3-D anionic partial structure with a B/P ratio of 2/3 and an unprecedented fifteen mer tetrahedral fundamental building unit (FBU) [B6P9O36(OH)3] exists in this compound. NH4+ ions locate in the void space to balance the negative charge of the inorganic framework. The compound is further characterized by powder XRD, ICP, CHN, TGA and IR analyses. Magnetic study reveals that MnBPO-CJ31 shows interesting canted antiferromagnetic behaviour at low temperature.

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U2 - 10.1039/c0dt01475c

DO - 10.1039/c0dt01475c

M3 - Article

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SN - 1477-9226

VL - 40

SP - 2549

EP - 2554

JO - Dalton Transactions

JF - Dalton Transactions

IS - 11

ER -

(NH₄)₆[Mn₃B₆P₉O ₃₆(OH)₃]·4H₂O: A new open-framework manganese borophosphate synthesized by using boric acid flux method

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