NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

Jun Hua Wang; Jian Wen Cheng; Qi Wei; Huan He; Bai Feng Yang; Guo Yu Yang

doi:10.1002/ejic.201402318

NaB₃O₅·0.5H₂O and NH₄NaB₆O₁₀: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

Jun Hua Wang, Jian Wen Cheng^*, Qi Wei, Huan He, Bai Feng Yang, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Two new cluster open framework borates, NaB₃O₅·0.5H₂O (1) and NH₄NaB₆O₁₀ (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B₃O₇ and B₆O₁₃ cluster units for 1 and 2, in which the B₃O₇ and B₆O₁₃ clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

Original language	English
Pages (from-to)	4079-4083
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Volume	2014
Issue number	25
DOIs	https://doi.org/10.1002/ejic.201402318
Publication status	Published - 1 Sept 2014

Keywords

Borates
Chirality
Luminescence
Open frameworks
Topochemistry

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10.1002/ejic.201402318

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title = "NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units",

abstract = "Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.",

keywords = "Borates, Chirality, Luminescence, Open frameworks, Topochemistry",

author = "Wang, {Jun Hua} and Cheng, {Jian Wen} and Qi Wei and Huan He and Yang, {Bai Feng} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2014",

month = sep,

day = "1",

doi = "10.1002/ejic.201402318",

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volume = "2014",

pages = "4079--4083",

journal = "European Journal of Inorganic Chemistry",

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publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - NaB3O5·0.5H2O and NH4NaB6O10

T2 - Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

AU - Wang, Jun Hua

AU - Cheng, Jian Wen

AU - Wei, Qi

AU - He, Huan

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2014/9/1

Y1 - 2014/9/1

N2 - Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

AB - Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

KW - Borates

KW - Chirality

KW - Luminescence

KW - Open frameworks

KW - Topochemistry

UR - http://www.scopus.com/inward/record.url?scp=85027930163&partnerID=8YFLogxK

U2 - 10.1002/ejic.201402318

DO - 10.1002/ejic.201402318

M3 - Article

AN - SCOPUS:85027930163

SN - 1434-1948

VL - 2014

SP - 4079

EP - 4083

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 25

ER -

NaB₃O₅·0.5H₂O and NH₄NaB₆O₁₀: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

Abstract

Keywords

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