TY - JOUR
T1 - N-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl} azanide trichloridostannate(II)
AU - Ma, Xiaoli
AU - Sun, Shuai
AU - Hao, Pengfei
AU - Yang, Ying
AU - Yang, Zhi
PY - 2012/6
Y1 - 2012/6
N2 - In the title compound, (C28H43N2) [SnCl3], two pairs of molecular species are present in the asymmetric unit. The employed α-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N - C= 1.264 (4) and 1.516 (4) Å]. One of the C=N double bonds was oxidized to C - N, which is consistent with the bond length of 1.516 (4) Å. Meanwhile SnIV was reduced to SnII. The (SnCl)3 - anion is trigonal-pyramidal. In the crystal, molecules are linked by C - H⋯Cl, N - H⋯Cl, N - H⋯N and C - H⋯N bonds. The crystal studied was twinned by pseudo-merohedry.
AB - In the title compound, (C28H43N2) [SnCl3], two pairs of molecular species are present in the asymmetric unit. The employed α-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N - C= 1.264 (4) and 1.516 (4) Å]. One of the C=N double bonds was oxidized to C - N, which is consistent with the bond length of 1.516 (4) Å. Meanwhile SnIV was reduced to SnII. The (SnCl)3 - anion is trigonal-pyramidal. In the crystal, molecules are linked by C - H⋯Cl, N - H⋯Cl, N - H⋯N and C - H⋯N bonds. The crystal studied was twinned by pseudo-merohedry.
UR - http://www.scopus.com/inward/record.url?scp=84862290426&partnerID=8YFLogxK
U2 - 10.1107/S1600536812014729
DO - 10.1107/S1600536812014729
M3 - Article
AN - SCOPUS:84862290426
SN - 1600-5368
VL - 68
SP - m719-m720
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 6
ER -