Magnetostructural investigations into an S = 1/2 sheet and a tetranuclear butterfly cluster

Tony D. Keene; Yu Heng Deng; Feng Ge Li; Yan Feng Ding; Biao Wu; Shi Xia Liu; Christina Ambrus; Oliver Waldmann; Silvio Decurtins; Xiao Juan Yang

doi:10.1016/j.ica.2008.10.009

Magnetostructural investigations into an S = 1/2 sheet and a tetranuclear butterfly cluster

Tony D. Keene, Yu Heng Deng^*, Feng Ge Li, Yan Feng Ding, Biao Wu, Shi Xia Liu, Christina Ambrus, Oliver Waldmann, Silvio Decurtins, Xiao Juan Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.

Original language	English
Pages (from-to)	2265-2269
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	362
Issue number	7
DOIs	https://doi.org/10.1016/j.ica.2008.10.009
Publication status	Published - 15 May 2009
Externally published	Yes

Keywords

Copper(II)
Molecular magnetism

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10.1016/j.ica.2008.10.009

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title = "Magnetostructural investigations into an S = 1/2 sheet and a tetranuclear butterfly cluster",

abstract = "We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.",

keywords = "Copper(II), Molecular magnetism",

author = "Keene, {Tony D.} and Deng, {Yu Heng} and Li, {Feng Ge} and Ding, {Yan Feng} and Biao Wu and Liu, {Shi Xia} and Christina Ambrus and Oliver Waldmann and Silvio Decurtins and Yang, {Xiao Juan}",

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doi = "10.1016/j.ica.2008.10.009",

language = "English",

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TY - JOUR

T1 - Magnetostructural investigations into an S = 1/2 sheet and a tetranuclear butterfly cluster

AU - Keene, Tony D.

AU - Deng, Yu Heng

AU - Li, Feng Ge

AU - Ding, Yan Feng

AU - Wu, Biao

AU - Liu, Shi Xia

AU - Ambrus, Christina

AU - Waldmann, Oliver

AU - Decurtins, Silvio

AU - Yang, Xiao Juan

PY - 2009/5/15

Y1 - 2009/5/15

N2 - We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.

AB - We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.

KW - Copper(II)

KW - Molecular magnetism

UR - http://www.scopus.com/inward/record.url?scp=64749108305&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2008.10.009

DO - 10.1016/j.ica.2008.10.009

M3 - Article

AN - SCOPUS:64749108305

SN - 0020-1693

VL - 362

SP - 2265

EP - 2269

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 7

ER -

Magnetostructural investigations into an S = 1/2 sheet and a tetranuclear butterfly cluster

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Keywords

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