Luminescence blue-shift of CdSe nanowires beyond the quantum confinement regime

Yuan Yan, Zhi Min Liao*, Ya Qing Bie, Han Chun Wu, Yang Bo Zhou, Xue Wen Fu, Da Peng Yu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

Photoluminescence (PL) properties of individual CdSe nanowires with diameters beyond the quantum confinement regime have been studied. A blue-shift in the PL spectra was observed with decreasing nanowire diameter. We attribute the blue-shift to band-filling effect. Carrier density induced by surface vacancy doping and laser excitation is found to be high enough to meet the criterion of the band-filling effect and increases with decreasing nanowire diameter. Temperature dependent PL analysis and characterizations of a single CdSe nanowire based field-effect transistor were also performed.

Original languageEnglish
Article number103103
JournalApplied Physics Letters
Volume99
Issue number10
DOIs
Publication statusPublished - 5 Sept 2011
Externally publishedYes

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